2022
S. Petrovskii, V. Khistiaeva, A. Paderina, E. Abramova and E. Grachova, Post-Functionalization of Organometallic Complexes via Click-Reaction, Molecules, 27 (2022) 6494; DOI: 10.3390/molecules27196494
S. Petrovskii, A. Senchukova, V. Sizov, A. Paderina, M. Luginin, E. Abramova and E. Grachova, Efficient photoswitchable organometallic complexes with azobenzene and stilbene units: the case of Au(I), Mol. Syst. Des. Eng., 7 (2022) 1249-1262; DOI: 10.1039/D2ME00071G
A. Surkova, A. Bogomolov, A. Paderina, V. Khistiaeva, E. Boichenko, E. Grachova, D. Kirsanov, Optical multisensor system based on lanthanide(III) complexes as near-infrared light sources for analysis of milk, Chemosensors, 10(7) (2022) 288; DOI: 10.3390/chemosensors10070288
A.Yu. Baranov, S.O. Slavova, A.S. Berezin, S.K. Petrovskii, D.G. Samsonenko, I.Yu. Bagryanskaya, V.P. Fedin, E.V. Grachova and A.V. Artem’ev, Controllable synthesis and luminescent behavior of tetrahedral Au@Cu4 and Au@Ag4 clusters supported by tris(2-pyridyl)phosphine, Inorg. Chem., 61 (2022) 10925-10933; DOI: 10.1021/acs.inorgchem.2c01474
A. Paderina, R. Ramazanov, R. Valiev, C. Müller and E. Grachova, So Close, Yet so Different: How One Donor Atom Changes Significantly the Photophysical Properties of Mononuclear Cu(I) Complexes, Inorg. Chem., 61(3) (2022) 11629-11638; DOI: 10.1021/acs.inorgchem.2c01145,
ON COVER
Kritchenkov, I. S.; Melnikov, A. S.; Serdobintsev, P. S.; Khodorkovskii, M. A.; Pavlovskii, V. V; Porsev, V. V; Tunik, S. P., Energy Transfer Processes in Excited States of {[Ir(N^C)2(N^N)]-Rhodamine} Dyad: Experimental and Theoretical Study, ChemPhotoChem, XX (2022) XXXX; DOI: 10.1002/cptc.202200048
Kritchenkov, I. S.; Mikhnevich, V. G.; Stashchak, V. S.; Solomatina, A. I.; Kozina, D. O.; Sokolov, V. V; Tunik, S. P., Novel NIR-Phosphorescent Ir(III) Complexes: Synthesis, Characterization and Their Exploration as Lifetime-Based O2 Sensors in Living Cells, Molecules, 27(10) (2022) 3156; DOI: 10.3390/molecules27103156
A. Paderina, A. Melnikov, S. Slavova, V. Sizov, V. Gurzhiy, S. Petrovskii, M. Luginin, O. Levin, I. Koshevoy and E. Grachova,
The tail wags the dog: the far periphery of the coordination environment manipulates the photophysical properties of heteroleptic Cu(I) complexes, Molecules, 27(7) (2022) 2250; DOI: 10.3390/molecules27072250
Hsia-An Lee, Peng-Yi Lin, Anastasia I. Solomatina, Igor O. Koshevoy, Sergey P. Tunik, Hui-Wen Lin, Sheng-Wei Pan, and Mei-Lin Ho,
Glucose Sensing in Human Whole Blood Based on Near-Infrared Phosphors and Outlier Treatment with the Programming Language "R", ACS Omega, 7(1) (2022) 198-206; DOI: 10.1021/acsomega.1c04344
A.I. Solomatina, D.O. Kozina, V.V. Porsev and S.P. Tunik,
pH-Responsive N^C-Cyclometalated Iridium(III) Complexes: Synthesis, Photophysical Properties, Computational Results, and Bioimaging Application, Molecules, 27(1) (2022) 232; DOI: 10.3390/molecules27010232
M.A. Kinzhalov, E.V. Grachova and K.V. Luzyanin, Tuning the Luminescence of Transition Metal Complexes with Acyclic Diaminocarbene Ligands, Inorg. Chem. Front., 9 (2022) 417-439; DOI: 10.1039/D1QI01288F
Anastasia I. Solomatina, Pavel S. Chelushkin, Shih-Hao Su, Cheng-Ham Wu, Pi-Tai Chou and Sergey P. Tunik, The Combined Fluorophore and Phosphor Conjugation: A New Design Concept for Simultaneous and Spatially Localized Dual Lifetime Intracellular Sensing of Oxygen and pH, Chem. Comm., 58 (2022) 419-422; DOI: 10.1039/D1CC06132A
Sergey P. Tunik, Pavel S. Chelushkin, Julia R. Shakirova, Ilya Kritchenkov and Vadim A. Baigildin, Phosphorescent NIR emitters for biomedicine: applications, advances and challenges, Dalton Trans., 51 (2022) 1257-1280; DOI: 10.1039/D1DT03077A,
2021 Frontier and Perspective articles
2021
E.O. Abramova, A.V. Paderina, S.O. Slavova, E.A. Kostenko, E.V. Eliseenkov, S.K. Petrovskii, A.Yu. Gitlina, V.P. Boyarskiy, and E.V. Grachova, Just add the gold: aggregation-induced emission properties of alkynylphosphine Au(I) complexes functionalized with phenylene-terpyridine subunits, Inorg. Chem., 60(24) (2021) 18715-18725; DOI: 10.1021/acs.inorgchem.1c02125
E.M. Baranovskii, V.V. Khistiaeva, K.V. Deriabin, S.K. Petrovskii, I.O. Koshevoy, I.E. Kolesnikov, E.V. Grachova and R.M. Islamova, Re(I) complexes as Backbone Substituents and Cross-linking Agents for Hybrid Luminescent Polysiloxanes and Silicone Rubbers, Molecules, 26 (2021) 6866; DOI: 10.3390/molecules26226866
M. Beliaeva, A. Belyaev, E. Grachova, A. Steffen, I. Koshevoy, Ditopic phosphide oxide group: a rigidifying Lewis base to switch luminescence and reactivity of a disilver complex, J. Am. Chem. Soc., 143(37) (2021) 15045-15055; DOI: 10.1021/jacs.1c04413
A.A. Elistratova, I.S. Kritchenkov, A.A. Lezov, A.S. Gubarev, A.I. Solomatina, D. V. Kachkin, N.A. Shcherbina, Y.-C. Liao, Y.-C. Liu, Y.-Y. Yang, N. V. Tsvetkov, P.S. Chelushkin, P.-T. Chou, S.P. Tunik, Lifetime oxygen sensors based on block copolymer micelles and non-covalent human serum albumin adducts bearing phosphorescent near-infrared iridium(III) complex,
Eur. Polym. J., 159 (2021) 110761; DOI: 10.1016/j.eurpolymj.2021.110761
Cheng-Ham Wu, K.S. Kisel, Muthu Kumar Thangavel, Yi-Ting Chen, Kai-Hsin Chang, Ming-Rung Tsai, Chia-Yu Chu, Yu-Fang Shen, Pei-Chun Wu, Tzu-Ming Liu, J. Jänis, E.V. Grachova, J.R. Shakirova, S.P. Tunik, I.O. Koshevoy, Pi-Tai Chou, Functionalizing collagen with vessel-penetrating two-photon phosphorescence probes: A new in vivo strategy to map oxygen concentration in tumor microenvironment and tissue ischemia,
Adv. Sci., 8(20) (2021) 2102788; DOI: 10.1002/advs.202102788
A.A. Surkova, A.V. Paderina, A.V. Legin, E.V. Grachova, and D.O. Kirsanov,
Cu(I)-based molecular emitters for quantification of fluoride and phosphate in surface waters,
Measurement, 184 (2021) 109976; DOI: 10.1016/j.measurement.2021.109976
Mosiagin I.P., Tomashenko O.A., Spiridonova D.V., Novikov M.S., Tunik S.P., Khlebnikov A.F.,
Free-radical cyclization approach to polyheterocycles containing pyrrole and pyridine rings,
Beilstein J. Org. Chem., 17 (2021) 1490-1498; DOI: 10.3762/bjoc.17.105
T. Eskelinen, S. Buss, S. K. Petrovskii, E. V. Grachova, M. Krause, L. Kletsch, A. Klein, C. A. Strassert, I. O. Koshevoy and P. Hirva,
Photophysics and Excited State Dynamics of Cyclometalated [M(Phbpy)(CN)] (M = Ni, Pd, Pt) Complexes: A Theoretical and Experimental Study,
Inorg. Chem., 60(12) (2021) 8777-8789; DOI: 10.1021/acs.inorgchem.1c00680
I.S. Kritchenkov, A.I. Solomatina, D.O. Kozina, V.V. Porsev, V.V. Sokolov, M.V. Shirmanova, M.M. Lukina, A.D. Komarova, V.I. Shcheslavskiy, T.N. Belyaeva, I.K. Litvinov, A.V. Salova, E.S. Kornilova, D.V. Kachkin, and S.P. Tunik,
Biocompatible Ir(III) Complexes as Oxygen Sensors for Phosphorescence Lifetime Imaging, Molecules, 26(10) (2021) 2898; DOI: 10.3390/molecules26102898
Kuznetsov, K. M.; Kritchenkov, I. S.; Shakirova, J. R.; Gurzhiy, V. V; Pavlovskiy, V. V; Porsev, V. V; Sokolov, V. V; Tunik, S. P.,
Red-to-NIR Iridium(III) Emitters: Synthesis, Photophysical and Computational Study, the Effects of Cyclometallating and β-Diketonate Ligands,
Eur. J. Inorg. Chem., 2021(22) (2021) 2163-2170; DOI: 10.1002/ejic.202100189
A.V. Paderina, I.O. Koshevoy and E.V. Grachova,
Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear
coinage metal complexes, Dalton Trans., 50 (2021) 6003-6033; DOI: 10.1039/D1DT00749A,
2021 Frontier and Perspective articles and Dalton Transactions HOT articles, ON COVER
Diana Temerova, Kristina S. Kisel, Toni Eskelinen, Alexei S. Melnikov, Niko Kinnunen, Pipsa Hirva, Julia R. Shakirova, Sergey P. Tunik, Elena V. Grachova, Igor O. Koshevoy,
Diversifying the luminescence of phenanthro-diimine ligands in zinc complexes,
Inorg. Chem. Front., 8 (2021) 2549-2560; DOI: 10.1039/D1QI00149C
I.O. Koshevoy, V. Sivchik, A. Kochetov, T. Eskelinen, K.S. Kisel, A.I. Solomatina, E.V. Grachova, S.P. Tunik, P. Hirva,
Modulation of metallophilic and ππ interactions in platinum cyclometalated luminophores with halogen bonding,
Chem. Eur. J., 27(5) (2021) 1787-1794; DOI: 10.1002/chem.202003952
D.O. Kozina, J.R. Shakirova, E.E. Galenko, V.V. Porsev, V.V. Gurzhiy, A.F. Khlebnikov, S.P. Tunik,
Unusual Reactivity and Photophysical Properties of the Pt(II) Pincer Complexes Containing 6,6'-diphenyl-2,2'-bipyridine ligands,
Eur. J. Inorg. Chem., 1 (2021) 117-125; DOI: 10.1002/ejic.202000827,
ON COVER
2020
S. Petrovskii, V. Khistiaeva, A. Sizova, V. Sizov, A. Paderina, I. Koshevoy, K. Monakhov, E. Grachova,
Hexavanadate-Organogold(I) Hybrid Compounds: Synthesis by the Azide-Alkyne Cycloaddition and Density Functional Theory Study of an Intriguing Electron Density Distribution,
Inorg. Chem., 59(22) (2020) 16122-16126; DOI: 10.1021/acs.inorgchem.0c02621,
ON COVER
Julia R. Shakirova, Zohreh Hendi, Daniil D. Zhukovsky, Victor V. Sokolov, Sirous Jamali, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik,
NIR emitting platinum pincer complexes based on the N^N^C ligand containing {benz[4,5]imidazo[1,2-a]pyrazin} aromatic system; synthesis, characterization and photophysical study, Inorg. Chim. Acta, 511 (2020) 119776; DOI: 10.1016/j.ica.2020.119776
J.R. Shakirova, S. Nayeri, S. Jamali, V.V. Porsev, V.V. Gurzhiy, O.V. Levin, I.O. Koshevoy, S.P. Tunik,
Targeted Synthesis of NIR Luminescent Rhenium cis,trans-[Re(N^N)(CO)2(L)2]n+ Complexes containing N-Donor Axial Ligands: Photophysical, Electrochemical and Theoretical Studies,
ChemPlusChem 85(11) (2020) 2518-2527; DOI: 10.1002/cplu.202000597
A.I. Solomatina, A.D. Slobodina, E.V. Ryabova, O.I. Bolshakova, P.S. Chelushkin, S.V. Sarantseva, S.P. Tunik,
Blood-Brain Barrier Penetrating Luminescent Conjugates Based on Cyclometalated Platinum(II) Complexes,
Bioconjugate Chem., 31(11) (2020) 2628-2637; DOI: 10.1021/acs.bioconjchem.0c00542
Chapaikina, S.A., Solomatina, A.I., Tunik, S.P.,
Reaction of Cyclometalated Phosphine Chloride Iridium(III) Complexes with Imidazole,
Russ. J. Gen. Chem. Int. Ed., 90(6) (2020) 1005-1011; DOI: 10.1134/S1070363220060110
S.K. Petrovskii, A.V. Paderina, A.A. Sizova, A.Yu. Baranov, A.A. Artem’ev, V.V. Sizov and E.V. Grachova,
Luminescence behaviour of Au(I)-Cu(I) heterobimetallic coordination polymers based on alkynyl-tris(2-pyridyl)phosphine Au(I) complexes,
Dalton Trans., 49 (2020) 13430-13439; DOI: 10.1039/D0DT02583F
Filipp Temerov, Khai Pham, Paxton Juuti, Jyrki Mäkelä, Elena Grachova, Santosh Kumar, Salvador Eslava, Jarkko Saarinen,
Silver Decorated TiO2 Inverse Opal Structure for Visible Light Induced Photocatalytic Degradation of Organic Pollutant and Hydrogen Evolution,
ACS Appl. Mater. Inter., 12(37) (2020) 41200-4121; DOI: 10.1021/acsami.0c08624
I. Kritchenkov, A. Elistratova, V. Sokolov, P. Chelushkin, M. Shirmanova, M. Lukina, V. Dudenkova, V. Shcheslavskiy,
S. Kalinina, K. Reess, A. Rueck and S. Tunik,
Biocompatible Phosphorescent Ir(III) Oxygen Sensor Functionalized with Oligo(ethylene glycol) Groups: Synthesis, Photophysics and Application in PLIM Experiments,
New J. Chem., 44 (2020) 10459-10471; DOI: 10.1039/D0NJ01405B
Marina V. Shirmanova, Vladislav I. Shcheslavskiy, Maria M. Lukina, Varvara V. Dudenkova, Ilya S. Kritchenkov, Anastasia I. Solomatina, Sergey P. Tunik,
Molecular oxygen mapping in biological samples by time-correlated single photon counting technique and Ir(III)-based complexes,
Proc. SPIE 11234, Optical Biopsy XVIII: Toward Real-Time Spectroscopic Imaging and Diagnosis, (2020) 112340G; DOI: 10.1117/12.2549248
Ilya S. Kritchenkov, Daniil D. Zhukovsky, Abdelrahman Mohamed, Viktor A. Korzhikov-Vlakh, Tatiana B. Tennikova, Antonina Lavrentieva, Thomas Scheper, Vladimir V. Pavlovskiy,
Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik,
Functionalized Pt(II) and Ir(III) NIR Emitters and Their Covalent Conjugates with Polymer-Based Nanocarriers,
Bioconjugate Chem., 31(5) (2020) 1327-1343; DOI: 10.1021/acs.bioconjchem.0c00020
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov and Sergey P Tunik,
Luminescent Organic Dyes Containing Phenanthro[9,10-D]Imidazole Core and [Ir(N^C)2(N^N)]+ Complexes Based on the Cyclometalating and Diimine Ligands of This Type,
Dalton Trans., 49 (2020) 6751-6763; DOI: 10.1039/D0DT00568A
A.Yu. Gitlina, A. Surkova, M.V. Ivonina, V.V. Sizov, S.K. Petrovskii, A. Legin, G.L. Starova, I.O. Koshevoy, E.V. Grachova, and D.O. Kirsanov,
Cyclometalated Ir(III) complexes as tuneable multiband light sources for optical multisensor systems: feasibility study,
Dyes and Pigments, (2020) 108428; DOI: 10.1016/j.dyepig.2020.108428
Sara Nayeri, Sirous Jamali, Ali Jamjah, Julia R. Shakirova, Sergey P. Tunik, Vladislav Gurzhiy, Hamidreza Samouei, and Hamid R. Shahsavari,
Five- and Six-Coordinated Silver(I) Complexes Formed by a Metallomacrocyclic Ligand with a 'Au2N2' Donor Group: Observation of Pendulum and Linear Motions and Dual Phosphorescence,
Inorg. Chem., 59(8) (2020) 5702-5712; DOI: 10.1021/acs.inorgchem.0c00482
Julia R. Shakirova, Amir Sadeghi, Alla A. Koblova, Pavel S. Chelushkin, Elisa Toropainen, Shirin Tavakoli, Leena-Stiina Kontturi, Tatu Lajunen, Sergey P. Tunik and Arto Urtti,
Design and synthesis of lipid-mimetic cationic iridium complexes and their liposomal formulation for
in vitro and in vivo application in luminescent bioimaging,
RSC Adv., 10 (2020) 14431-14440; DOI: 10.1039/D0RA01114B
J.R. Shakirova, N.N. Shevchenko, V.A. Baigildin, P.S. Chelushkin, A.F. Khlebnikov, O.A. Tomashenko,
A.I. Solomatina, G.L. Starova, S.P. Tunik,
Eu-based Phosphorescence Lifetime Polymer Nanothermometer: a Nanoemulsion Polymerization Approach to Eliminate Quenching of Eu Emission in Aqueous Media,
ACS Appl. Polym. Mater., 2(2) (2020) 537-547; DOI: 10.1021/acsapm.9b00952
I.D. Strelnik, V.V. Sizov, V.V. Gurzhiy, A.S. Melnikov, I.E. Kolesnikov, E.I. Musina, A.A. Karasik, and E.V. Grachova,
Au(I) binuclear phosphine-alkynyl complexes templated on flexible cyclic phosphine ligand: synthesis and some features of solid-state luminescence,
Inorg. Chem., 59(1) (2020) 244-253; DOI: 10.1021/acs.inorgchem.9b02091
A. Belyaev, S.O. Slavova, I.V. Solovyev, V.V. Sizov, J. Jänisa E.V. Grachova, I.O. Koshevoy,
Solvatochromic dual luminescence of Eu-Au dyads decorated with chromophore phosphines,
Inorg. Chem. Front., 7 (2020) 140-149; DOI: 10.1039/c9qi01015g
Andreii S. Kritchenkov, Anton R. Egorov, Alexey A. Artemjev, Ilya S. Kritchenkov, Olga V. Volkova, Elena I. Kiprushkina, Ludmila A. Zabodalova, Elena P. Suchkova, Niyaz Z. Yagafarova, Alexander G. Tskhovrebov, Aleh V. Kurliuk, Tatsiana V. Shakola, Victor N. Khrustalev,
Novel heterocyclic chitosan derivatives and their derived nanoparticles: Catalytic and antibacterial properties,
Int. J. Biol. Macromol., 149 (2020) 682-692; DOI: 10.1016/j.ijbiomac.2019.12.277
Andreii S. Kritchenkov, Anton R. Egorov, Alexey A. Artemjev, Ilya S. Kritchenkov, Olga V. Volkova, Aleh V. Kurliuk, Tatsiana V. Shakola, Vasili V. Rubanik Jr, Vasili V. Rubanik, Alexander G. Tskhovrebov, Niyaz Z. Yagafarova, Victor N. Khrustalev,
Ultrasound-assisted catalyst-free thiol-yne click reaction in chitosan chemistry: Antibacterial and transfection activity of novel cationic chitosan derivatives and their based nanoparticles,
Int. J. Biol. Macromol., 143 (2020) 143-152; DOI: 10.1016/j.ijbiomac.2019.11.241
Butt M.A., Mamonova D., Petrov Y., Proklova A., Kritchenkov I., Manshina A., Banzer P., Leuchs G.,
Hybrid Orthorhombic Carbon Flakes Intercalated with Bimetallic Au-Ag Nanoclusters: Influence of Synthesis Parameters on Optical Properties,
Nanomaterials, 104 (2020) 1376; DOI: 10.3390/nano10071376
Vasileva A., Haschke S., Mikhailovskii V., Gitlina A., Bachmann J., Manshina A.,
Direct laser-induced deposition of AgPt@C nanoparticles on 2D and 3D substrates for electrocatalytic glucose oxidation,
Nano-Structures and Nano-Objects, 24 (2020) 100547; DOI: 10.1016/j.nanoso.2020.100547
2019
S. Nayeri, S. Jamali, V.V. Pavlovskiy, V.V. Porsev, R.A. Evarestov, K.S. Kisel, I.O. Koshevoy, J.R. Shakirova, and S.P. Tunik,
A rare example of Re(I) diimine complexes with unsupported coordinated phosphine oxide ligand: synthesis, structural
characterization, photophysical and theoretical study, Eur. J. Inorg. Chem., 39-40 (2019) 4350-4357;
DOI: 10.1002/ejic.201900617 Special Issue: EuChemS Inorganic Chemistry Celebrates IYPT
I.S. Kritchenkov, P.S. Chelushkin, V.V. Sokolov, V.V. Pavlovskiy, V.V. Porsev, R.A. Evarestov, S.P. Tunik, Near infrared
[Ir(N^C)2(N^N)]+ emitters and their noncovalent adducts with HSA: synthesis, photophysical and computational study,
Organometallics, 38(19) (2019) 3740-3751; DOI: 10.1021/acs.organomet.9b00480
E.V. Grachova,
Design of Supramolecular Cluster Compounds of Copper Subgroup Metals Based on Polydentate Phosphine Ligands,
Russ. J. Gen. Chem. Int. Ed., 89(6) (2019) 1102-1114; DOI: 10.1134/S1070363219060045
Themed issue dedicated to the 150th anniversary of Inorganic Chemistry Department of
St. Petersburg State University
Kunal Kumar, Daisuke Abe, Keiko Komori-Orisaku, Olaf Stefanczyk, Koji Nakabayashi, Julia R.Shakirova, Sergey P. Tunik, Shin-ichi Ohkoshi,
Neodymium beta-diketonate showing slow magnetic relaxation and acting as a ratiometric thermometer based on near-infrared emission,
RSC Adv., 9 (2019) 23444-23449; DOI: 10.1039/c9ra03276b
Andrey Belyaev, Ilya Kolesnikov, Alexei S. Melnikov, Vladislav V. Gurzhiy, Sergey P. Tunik, Igor O. Koshevoy,
Solution versus Solid-State Dual Emission of the Au(I)-Alkynyl Diphosphine Complexes via Modification of Polyaromatic Spacer,
New J. Chem., 43 (2019) 13741-13750; DOI: 10.1039/C9NJ03426A
Aleksei A. Titov, Oleg A. Filippov, Alexander F. Smol’yakov, Ivan A. Godovikov, Julia R. Shakirova, Sergey P. Tunik, Ivan S. Podkorytov and Elena S. Shubina,
Luminescent complexes of the trinuclear silver(I) and copper(I) pyrazolates supported with bis(diphenylphosphino)methane,
Inorg. Chem., 58(13) (2019) 8645-8656; DOI: 10.1021/acs.inorgchem.9b00991
Ilya S. Kritchenkov, Julia R. Shakirova and Sergey P. Tunik,
Efficient one-pot green synthesis of tetrakis(acetonitrile)copper(I) complex in aqueous media,
RSC Adv., 9 (2019) 15531-15535; DOI: 10.1039/c8ra10564b
G. Chakkaradhari, T. Eskelinen, C. Degbe, A. Belyaev, A.S. Melnikov, E.V. Grachova, S.P. Tunik, P. Hirva, I.O. Koshevoy,
Oligophosphine-thiocyanate copper(I) and silver(I) complexes and their borane derivatives showing delayed fluorescence,
Inorg. Chem., 58(6) (2019) 3646-3660; DOI: 10.1021/acs.inorgchem.8b03166
Galenko, E.E., Novikov, M.S., Shakirova, F.M., Shakirova, J.R., Kornyakov, I.V., Bodunov, V.A., Khlebnikov, A.F.,
Isoxazole Strategy for the Synthesis of 2,2′-Bipyridine Ligands: Symmetrical and Unsymmetrical 6,6′-Binicotinates, 2,2′-Bipyridine-5-carboxylates, and Their Metal Complexes,
J. Org. Chem., 84 (6) (2019) 3524-3536; DOI: 10.1021/acs.joc.9b00115
K.S. Kisel, A.S. Melnikov, E.V. Grachova, A.J. Karttunen, A. Doménech-Carbó, K.Yu. Monakhov, V.G. Semenov, S.P. Tunik, I.O. Koshevoy,
Supramolecular construction of cyanide-bridged ReI diimine multichromophores,
Inorg. Chem., 58(3) (2019) 1988-2000; DOI: 10.1021/acs.inorgchem.8b02974
Anastasia I. Solomatina, Vadim A. Baigildin, Daniil D. Zhukovsky, Dmitrii V. Krupenya, Elena I. Koshel, Vladislav I. Shcheslavskiy, Sergey P. Tunik, Pavel S. Chelushkin,
How to avoid protein aggregation to improve cellular uptake of albumin-based conjugates: towards the rational design of cell-penetrable phosphorescent probes,
Colloid Polym. Sci., 297 (2019) 325-337; DOI: 10.1007/s00396-018-4412-x
Chelushkin P.S., Tunik S.P.,
Phosphorescence Lifetime Imaging (PLIM): State of the Art and Perspectives,
In: Yamanouchi K., Tunik S., Makarov V., (eds) Progress in Photon Science. Recent Advances. Springer Series in Chemical Physics,
Springer, Cham, 119 (2019) 109-128; DOI: 10.1007/978-3-030-05974-3_6
A.I. Solomatina, P.S. Chelushkin, T.O. Abakumova, V.A. Zhemkov, Mee-Whi Kim, I. Bezprozvanny, V.V. Gurzhiy, A.S. Melnikov,
Y.A. Anufrikov, I.O. Koshevoy, Shih-Hao Su, Pi-Tai Chou, S.P. Tunik,
Reactions of Cyclometalated Platinum(II) [Pt(N^C)(PR3)Cl] Complexes with Imidazole and Imidazole-Conjugated Biomolecules:
Fine-Tuning Reactivity and Photophysical Properties via Ligand Design,
Inorg. Chem., 58 (2019) 204-217; DOI: 10.1021/acs.inorgchem.8b02204
2018
V.V. Khistiaeva, A.S. Melnikov, S.O. Slavova, V.V. Sizov, G.L. Starova, I.O. Koshevoy, and E.V. Grachova,
Heteroleptic β-diketonate Ln(III) complexes decorated by pyridyl substituted pyridazine ligand: synthesis, structure and luminescent properties,
Inorg. Chem. Front., 5 (2018) 3015-3027; DOI: 10.1039/C8QI00712H ON COVER
M.A. Zhukovskaya, D.D. Zhukovsky, V.V. Pavlovskiy, V.V. Porsev, R.A. Evarestov, S.P. Tunik,
Binuclear platinum(II) complexes based on a new bis-bidentate 3,6-di(thien-2-yl)pyridazine skeleton, a novel type of deep-red phosphorescent emitters:
Synthesis and non-empirical calculations,
Inorg. Chem. Commun., 98 (2018) 105-110; DOI: 10.1016/j.inoche.2018.10.002
Julia R. Shakirova, Elena V. Grachova, Vladislav V. Gurzhiy, Senthil Kumar Thangaraj, Janne Jänis, Alexey S. Melnikov, Antti J. Karttunen, Sergey P. Tunik, Igor O. Koshevoy,
Heterometallic cluster-capped tetrahedral assemblies with postsynthetic modification of the metal cores,
Angew. Chem. Int. Ed., 57 (2018) 14154-14158; DOI: 10.1002/anie.201809058
Ilya S. Kritchenkov, Anastasia Yu. Gitlina, Igor O. Koshevoy, Alexey S. Melnikov, and Sergey P. Tunik,
Luminescent Silver-Copper ‘Hourglass’ Hepta- and Decanuclear Alkynyl-Phosphine Clusters,
Eur. J. Inorg. Chem., 34 (2018) 3822-3828; DOI: 10.1002/ejic.201800631
I.O. Koshevoy, V. Sivchik, Rajib Sarker, Zong-Ying Liu, Kun-You Chung, E.V. Grachova, A.J. Karttunen, and Pi-Tai Chou,
Improvement of the photophysical performance of platinum cyclometalated complexes in halogen bonded adducts,
Chem. Eur. J., 24 (2018) 11475-11484; DOI: 10.1002/chem.201802182
Julia R. Shakirova, Olesya A. Tomashenko, Ekaterina E. Galenko,
Alexander F. Khlebnikov, Pipsa Hirva, Galina L. Starova, Shih-Hao Su, Pi-Tai Chou, Sergey P. Tunik,
Metalated Ir(III) complexes based on a luminescent diimine ligands; synthesis and photophysical study,
Inorg. Chem., 57 (2018) 6853-6864; DOI: 10.1021/acs.inorgchem.8b00390
K.S. Kisel, T. Eskelinen, W. Zafar, A.I. Solomatina, P. Hirva, E.V. Grachova, S.P. Tunik, I.O. Koshevoy,
Chromophore-functionalized phenanthro-diimine ligands and their Re(I) complexes,
Inorg. Chem., 57 (2018) 6349-6361; DOI: 10.1021/acs.inorgchem.8b00422
A.Yu. Gitlina, M.V. Ivonina, V.V. Sizov, G.L. Starova, A.P. Pushkarev, D. Volyniuk, S.P. Tunik, I.O. Koshevoy and E.V. Grachova,
The rare example of compact heteroleptic cyclometalated iridium(III) complex demonstrating well-separated dual emission,
Dalton Trans., 47 (2018) 7578-7586; DOI: 10.1039/C8DT01336E
A.I. Solomatina, Shih-Hao Su, M.M. Lukina, V.V. Dudenkova, V.I. Shcheslavskiy, Cheng-Ham Wu, P.S. Chelushkin, Pi-Tai Chou, I.O. Koshevoy and S.P. Tunik,
Water-soluble cyclometalated platinum(II) and iridium(III) complexes: synthesis, tuning of the photophysical properties, and
in vitro
and in vivo phosphorescence lifetime imaging,
RSC Adv., 8 (2018) 17224-17236; DOI: 10.1039/c8ra02742k
D.D. Zhukovsky, V.V. Sizov, G.L. Starova, S.P. Tunik, and E.V. Grachova,
Binuclear luminescent Pt(II) complexes based on substituted 3,6-diphenylpyridazines; synthesis and photophysical study,
J. Organomet. Chem., 867 (2018) 367-374; DOI: 10.1016/j.jorganchem.2017.12.023
K. Keller, A.V. Yakovlev, E.V. Grachova, and A.V. Vinogradov,
Inkjet Printing of Multicolor Daylight Visible Opal Holography,
Adv. Funct. Mater., (2018) 1706903; DOI: 10.1002/adfm.201706903
N. Glebko, Thuy Minh Dau, A.S. Melnikov, E.V. Grachova, I.V. Solovyev, A. Belyaev, A.J. Karttunen and I.O. Koshevoy,
Luminescence thermochromism of gold(I) phosphane-iodide complexes: a rule or an exception?,
Chem. Eur. J., 24 (2018) 3021-3029; DOI: 10.1002/chem.201705544
Julia R. Shakirova, Masaki Shimada, Dmitrii A. Olisov, Galina L. Starova, Hiroshi Nishihara, Sergey P. Tunik,
Dinuclear Diphosphine Complexes of Gold(I) Alkynyls, the Effects of Alkynyl Substituents onto Photophysical Behavior,
Z. Anorg. Allg. Chem., (2018) 308-316; DOI: 10.1002/zaac.201700415
I.V. Solovyev, A. Kondinski, K.Yu. Monakhov, I.O. Koshevoy and E.V. Grachova,
Synthesis, photophysical properties and cation-binding studies of bipyridine-functionalized gold(I) complexes,
Inorg. Chem. Front., 5 (2018) 160-171; DOI: 10.1039/C7QI00514H
I.O. Koshevoy, A. Belyaev, T. Eskelinen, Thuy Minh Dau, Y.Yu. Ershova, A.S. Melnikov, S.P. Tunik, and P. Hirva,
Cyanide-assembled d10 coordination polymers and cycles: excited state metallophilic modulation of solid-state luminescence,
Chem. Eur. J., 24 (2018) 1404-1415; DOI: 10.1002/chem.201704642
2017
Alexander A. Penney, Galina L. Starova, Elena V. Grachova, Vladimir V. Sizov, Mikhail A. Kinzhalov, and Sergey P. Tunik,
Gold(I) Alkynyls Supported by Mono- and Bidentate NHC Ligands: Luminescence and Isolation of Unprecedented Ionic Complexes,
Inorg. Chem., 56 (2017) 14771-14787; DOI: 10.1021/acs.inorgchem.7b01508
A. Belyaev, Yi-Ting Chen, Shih-Hao Su, Yu-Jui Tseng, A.J. Karttunen, S.P. Tunik, Pi-Tai Chou, I.O. Koshevoy,
The P-heterocyclic fluorophores, obtained via Cu(II)-mediated cyclization, are suitable for cell imaging due to their stability, water solubility and low toxicity,
Chem. Commun., 53 (2017) 10954-10957; DOI: 10.1039/C7CC06882D
Tunik S., Chelushkin P., Koshevoy I.,
Photophysical Properties of Triplet Emitters Based on Au-Cu, Au-Ag Supramolecular Complexes and Prospective of Application in Sensing,
Bioimaging, and OLEDs, In: Yamanouchi K. (eds) Progress in Photon Science. Springer Series in Chemical Physics, Springer, Cham
115 (2017) 109-123; DOI: 10.1007/978-3-319-52431-3_10
Julia R. Shakirova, Olesya A. Tomashenko, Elena V. Grachova, Galina L. Starova, Vladimir V. Sizov, Alexander F. Khlebnikov and Sergey P. Tunik,
Gold(I)-alkynyl complexes with a new type N-donor heterocyclic ligand: Synthesis and photophysical properties,
Eur. J. Inorg. Chem., 36 (2017) 4180-4186;
DOI: 10.1002/ejic.201700731
K.S. Kisel, A.S. Melnikov, E.V. Grachova, P. Hirva, S.P. Tunik, I.O. Koshevoy,
Linking Re(I) and Pt(II) chromophores with aminopyridines: a simple route to achieve a complicated photophysical behavior, Chem. Eur. J., 23 (2017) 11301-11311;
DOI: 10.1002/chem.201701539
A.I. Solomatina, I.O. Aleksandrova, A.J. Karttunen, S.P. Tunik, I.O. Koshevoy,
Dibenzothiophene-platinated complexes: probing the effect of ancillary ligands on the photophysical performance, Dalton Trans., 46 (2017) 3895-3905;
DOI: 10.1039/C7DT00349H
J.R. Shakirova, E.V. Grachova, V.V. Sizov, G.L. Starova, I.O. Koshevoy, A.S. Melnikov, M.C. Gimeno, A. Laguna, and S.P. Tunik,
Polynuclear cage-like Au(I) phosphane complexes based on S2− template; observation of multiple
luminescence in coordinated polyaromatic systems, Dalton Trans., 46 (2017) 2516-2523;
DOI: 10.1039/C6DT04126D
E.G. Vlakh, E.V. Grachova,
D.D. Zhukovsky, A.V. Hubina, J.R. Shakirova, A.S. Mikhailova, V.V. Sharoyko, S.P. Tunik, T.B. Tennikova,
Self-assemble nanoparticles based on polypeptides containing C-terminal luminescent Pt-cysteine complex,
Sci. Rep., (2017) 7:41991;
DOI: 10.1038/srep41991
Yi-Ting Chen, I.S. Krytchankou, A.J. Karttunen,
E.V. Grachova, S.P. Tunik, Pi-Tai Chou, and I.O. Koshevoy, Silver Alkynyl-Phosphine Clusters: an Electronic Effect of the
Alkynes Defines Structural Diversity, Organometallics, 36 (2017) 480-489;
DOI: 10.1021/acs.organomet.6b00866
A.I. Solomatina, P.S. Chelushkin, D.V. Krupenya, I.S. Podkorytov, T.O. Artamonova, V.V. Sizov, A.S. Melnikov, V.V. Gurzhiy, E.I. Koshel, V.I. Shcheslavskiy, S.P. Tunik,
Coordination to Imidazole Ring Switches On Phosphorescence of Platinum Cyclometalated Complexes: The Route to Selective Labeling of Peptides and Proteins via
Histidine Residues, Bioconjugate Chem., 28 (2017) 426-437; DOI: 10.1021/acs.bioconjchem.6b00598
S. Schlicht, A. Kireev, E. Grachova, S. Tunik, A. Manshina, J. Bachmann,
A model electrode of well-defined geometry prepared by direct laser-induced decoration of nanoporous templates with Au-Ag@C nanoparticles,
Nanotechnology, 28 (2017) 065405; DOI: 10.1088/1361-6528/aa536a
E.I. Koshel, P.S. Chelushkin, A.S. Melnikov, P.Yu. Serdobintsev, A.Yu. Stolbovaia, A.F. Saifitdinova, V.I. Shcheslavskiy,
O. Chernyavskiy, E.R. Gaginskaya, I.O. Koshevoy, S.P. Tunik,
Lipophilic phosphorescent gold(I) clusters as selective probes for visualization of lipid droplets by two-photon microscopy,
J. Photoch. Photobio. A, 332 (2017) 122-130; DOI: 10.1016/j.jphotochem.2016.08.017
2016
Bashouti M.Y., Povolotckaia A.V., Povolotskiy A.V., Tunik S.P., Christiansen S.H., Leuchs G., Manshina A.A.,
Spatially-controlled laser-induced decoration of 2D and 3D substrates with plasmonic nanoparticles,
RSC Advances, 6 (2016) 75681-75685; DOI: 10.1039/C6RA16585K
I. Strelnik, E. Musina, E. Grachova, A. Karasik, and O. Sinyashin,
Luminescent copper(I) and gold(I) complexes of 1,5-diaza-3,7-diphosphacyclooctanes,
Phosphrous, Sulfur, and Silicon, 191 (2016) 1518-1519; DOI: 10.1080/10426507.2016.1212346
Andrey Belyaev, Thuy Minh Dau, Janne Jänis, Elena V. Grachova, Sergey P. Tunik and Igor O. Koshevoy,
Low-nuclearity alkynyl d10 clusters supported by chelating multidentate phosphines,
Organometallics, 35 (2016) 3763-3774; DOI: 10.1021/acs.organomet.6b00701
R.R. Ramazanov, A.I. Kononov, A.M. Nesterenko, J.R. Shakirova, E.V. Grachova, I.O. Koshevoy and S.P. Tunik,
Luminescence Switching of an Au-Cu Supramolecular Complex: a Physical Insight,
J. Phys. Chem. C, 120 (2016) 25541-25547; DOI: 10.1021/acs.jpcc.6b08710
Ekaterina E. Galenko, Alexey V. Galenko, Alexander F. Khlebnikov, Mikhail S. Novikov, and Julia R. Shakirova,
Synthesis and intramolecular azo coupling of 4-diazopyrrole-2-carboxylates: selective approach to benzo and hetero [c]-fused 6H-pyrrolo[3,4-c]pyridazine-5-carboxylates,
J. Org. Chem., 81 (2016) 8495-8507; DOI: 10.1021/acs.joc.6b01662
I.D. Strelnik, V.V. Gurzhiy, V.V. Sizov, E.I. Musina, A.A. Karasik, S.P. Tunik, and E.V. Grachova,
A stimuli-responsive Au(I) complex based on aminomethylphosphine template: synthesis, crystalline phases and luminescent properties,
CrystEngComm, 18 (2016) 7629–7635; DOI: 10.1039/C6CE01272H
Thuy Minh Dau, Benjamin Darko Asamoah, A. Belyaev, Gomathy Chakkaradhari, P. Hirva, J. Jänis, E.V. Grachova, S.P. Tunik and I.O. Koshevoy,
Adjustable coordination of a hybrid phosphine-phosphine oxide ligand in luminescent Cu, Ag and Au complexes,
Dalton Trans., 45 (2016) 14160-14173; DOI: 10.1039/c6dt02435a
A.A. Penney, V.V. Sizov, E.V. Grachova, D.V. Krupenya, V.V. Gurzhiy, G.L. Starova and S.P. Tunik,
Aurophilicity in Action: Fine-tuning the Gold(I)–Gold(I) Distance in the Excited State to Modulate the Emission in a Series of Dinuclear Homoleptic Gold(I)–NHC complexes,
Inorg. Chem., 55(10) (2016) 4720-4732; DOI: 10.1021/acs.inorgchem.5b02722
ON COVER
I. Kondrasenko, Kun-you Chung, Yi-Ting Chen, J. Koivistoinen, E.V. Grachova, A.J. Karttunen, Pi-Tai Chou and I.O. Koshevoy,
Harnessing fluorescence versus phosphorescence ratio via ancillary ligand fine-tuned MLCT contribution,
J. Phys. Chem. C, 120(22) (2016) 12196-12206; DOI: 10.1021/acs.jpcc.6b03064
A.A. Makarova, E.V. Grachova, D. Niedzialek, A.I. Solomatina, S. Sonntag, A.V. Fedorov, O.Yu. Vilkov, V.S. Neudachina, C. Laubschat, S.P. Tunik, and D.V. Vyalikh,
A curious interplay in the films of N-heterocyclic carbene PtII complexes upon deposition of alkali metals,
Sci. Rep., (2016) 6:25548; DOI: 0.1038/srep25548
V. Fernández-Moreira, J. Cámara, E.S. Smirnova, I.O. Koshevoy, A. Laguna, S.P. Tunik, M.C. Blanco, M.C. Gimeno,
Tuning the energy emission from violet to yellow with bidentate phosphine gold(III) complexes,
Organometallics, 35 (2016) 1141-1150; DOI: 10.1021/acs.organomet.6b00135
V. Sivchik, E.V. Grachova, A.S. Melnikov, S.N. Smirnov, A.Yu. Ivanov, S.P. Tunik and I.O. Koshevoy,
Solid state and solution metallophilic aggregation of a cationic [Pt(NCN)]+ cyclometalated complex,
Inorg. Chem., 55(7) (2016) 3351-3363; DOI: 10.1021/acs.inorgchem.5b02713
Gomathy Chakkaradhari, Yi-Ting Chen, A.J. Karttunen, Minh Thuy Dau, J. Jänis, S.P. Tunik, Pi-Tai Chou, Mei-Lin Ho and I.O. Koshevoy,
Luminescent Triphosphine Cyanide d10 Metal Complexes,
Inorg. Chem., 55(5) (2016) 2174-2184; DOI: 10.1021/acs.inorgchem.5b02581
E.I. Musina, A.V. Shamsieva, I.D. Strelnik, T.P. Gerasimova, D.B. Krivolapov, I.E. Kolesnikov, E.V. Grachova, S.P. Tunik,
C. Bannwarth, S. Grimme, S.A. Katsyuba, A.A. Karasik and O.G.Sinyashin,
Synthesis of novel pyridyl containing phospholanes and their polynuclear luminescent copper(I) complexes,
Dalton Trans., 45 (2016) 2250-2260; DOI: 10.1039/C5DT03346B
Koshel E.I., Tomashenko O.A., Khlebnikov A.F., Gaginskaya E.R., Saifitdinova A.F., and Tunik S.P.,
A new nuclear heterocyclic fluorescent dye – a promising tool for karyology and cytogenetics,
Chromosome Res., 24(suppl 1) (2016) 29; DOI: 10.1007/s10577-016-9532-x
A.A. Beljaev, D.V. Krupenya, E.V. Grachova, V.V. Gurzhiy, A.S. Melnikov, P.Yu. Serdobintsev, E.S. Sinitsyna, E.G. Vlakh, T.B. Tennikova and S.P. Tunik,
Supramolecular AuI-CuI complexes as new luminescent labels for covalent bioconjugation,
Bioconjugate Chem., 27(1) (2016) 143-150; DOI: 10.1021/acs.bioconjchem.5b00563
ON COVER
2015
V.V. Sivchik, A.I. Solomatina, Yi-Ting Chen, A.J. Karttunen, S.P. Tunik, Pi-Tai Chou and I.O. Koshevoy,
Halogen bond as luminescence amplifier: a case study using platinum cyclometalated complex as a paradigm,
Angew. Chem. Int. Ed., 54(47) (2015) 14057-14060; DOI: 10.1002/anie.201507229
Olesya A. Tomashenko, Alexander F. Khlebnikov, Ivan P. Mosiagin, Mikhail S. Novikov, Elena V. Grachova, Julia R. Shakirova and Sergey P. Tunik,
A new heterocyclic skeleton with highly tunable absorbtion/emission wavelength via H-bonding,
RCS Adv., 5 (2015) 94551-94561; DOI: 10.1039/C5RA17755C
B.T. Heaton, E.V. Grachova, S.P. Tunik and I.S. Podkorytov,
Comment on “The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]” by
Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D,
Dalton Trans., 44 (2015) 16611-16613; DOI: 10.1039/C5DT01099C
Ilya S. Krytchankou, Igor O. Koshevoy, Vladislav V. Gurzhiy, Vladimir A. Pomogaev, Sergey P. Tunik,
Luminescence solvato- and vapochromism of alkynyl-phosphine copper clusters,
Inorg. Chem., 54 2015 8288-8297; DOI: 10.1021/acs.inorgchem.5b00239
A. Manshina, A. Povolotskiy, A. Povolotckaia, A. Kireev, Yu. Petrov, S. Tunik,
Annealing effect: Controlled modification of the structure, composition and plasmon resonance of hybrid Au-Ag/C nanostructures,
Appl. Surf. Sci., 353 2015 11-16; DOI: 10.1016/j.apsusc.2015.06.048
Gomathy Chakkaradhari, Andrey A. Belyaev, Antti. J. Karttunen, Vasily Sivchik, Sergey P. Tunik and Igor O. Koshevoy,
Alkynyl triphosphine copper complexes: synthesis and photophysical studies,
Dalton Trans., 44 2015 13294-13304; DOI: 10.1039/C5DT01870F
A.A. Manshina, E.V. Grachova, A.V. Povolotskiy, A.V. Povolotckaia, Yu.V. Petrov, I.O. Koshevoy, A.A. Makarova, D.V. Vyalikh, and S.P. Tunik,
Laser-induced transformation of supramolecular complexes: a novel approach to control formation of hybrid multi-yolk-shell
Au-Ag@a-C:H nanostructures for stable SERS substrates,
Sci. Rep., 2015 5:12027; DOI: 10.1038/srep12027
P.S. Chelushkin, N.V. Nukolova, A.S. Melnikov, P.Yu. Serdobintsev, P.A. Melnikov, D.V. Krupenya, I.O. Koshevoy, S.V. Burov, and S.P. Tunik,
HSA-based Phosphorescent Probe for Two-Photon in vitro Visualization,
J. Inorg. Biochem., 149 2015 108-111; DOI: 10.1016/j.jinorgbio.2015.03.014
M. Y. Bashouti, A. Manshina, A. Povolotckaia, A. Povolotskiy, A. Kireev, Y. Petrov, M. Mačković, E. Spiecker, I. Koshevoy, S. Tunik and S. Christiansen,
Direct laser writing of μ-chips based on hybrid C–Au–Ag nanoparticles for express analysis of hazardous and biological substances,
Lab on a Chip, 15 2015 1742-1747; DOI: 10.1039/c4lc01376j
K.S. Kisel, G.Linti, G.L. Starova, V.V. Sizov, A.S. Melnikov, A.P. Pushkarev, M.N. Bochkarev, E.V. Grachova and S.P. Tunik,
Synthesis, structure and photophysical properties of Eu and Lu diketonates with neutral polydentate imidazolyl-methanamine ligand,
Eur. J. Inorg. Chem., 10 2015 1734-1743; DOI: 10.1002/ejic.201403186
A. A. Makarova, E. V. Grachova, V. S. Neudachina, L. V. Yashina, A. Blüher, S. L. Molodtsov, M. Mertig, H. Ehrlich, V. K. Adamchuk, C. Laubschat and D. V. Vyalikh,
Insight into bio-metal interface formation in vacuo: Interplay of S-layer protein with copper and iron,
Sci. Rep., 2015 5:8710; DOI: 10.1038/srep08710
Ilya Kondrasenko, Kristina S. Kisel, Antti J. Karttunen, Janne Jänis, Elena V. Grachova, Sergey P. Tunik and Igor O. Koshevoy,
Rhenium(I) complexes with alkynyl-phosphine ligands: structural, photophysical and theoretical studies,
Eur. J. Inorg. Chem., 5 2015 864-875; DOI: 10.1002/ejic.201403053
A.I. Solomatina, D.V. Krupenya, V.V. Gurzhiy, I. Zlatkin, A.P. Pushkarev, M.N. Bochkarev, N.A. Besley, E. Bichoutskaia, S.P. Tunik,
Cyclometallated platinum(II) complexes containing NHC ligands; synthesis, characterization, photophysics and their application as emitters in OLEDs,
Dalton Trans., 44 2015 7152-7162; DOI: 10.1039/C4DT03106G
ON COVER
2014
Thuy Minh Dau, Yi-An Chen, A.J. Karttunen, E.V. Grachova, S.P. Tunik, Ke-Ting Lin, Wen-Yi Hung, Pi-Tai Chou, T.A. Pakkanen and I.O. Koshevoy,
Tetragold(I) complexes: solution isomerization and tunable solid-state luminescence,
Inorg. Chem., 53(24) 2014 12720-12731; DOI: 10.1021/ic501470v
Anna Lähde, Igor Koshevoy, Tommi Karhunen, Tiina Torvela, Tapani A. Pakkanen, Jorma Jokiniemi,
Aerosol-assisted synthesis of gold nanoparticles,
J. Nanopart. Res., 2014 16:2716 DOI: 10.1007/s11051-014-2716-4
Leonid V. Romashov, Levon L. Khemchyan, Evgeniy G. Gordeev, Igor O. Koshevoy,
Sergey P. Tunik, and Valentine P. Ananikov,
Design of a Bimetallic Au/Ag System for Dechlorination of Organochlorides: Experimental and Theoretical Evidence for the Role
of the Cluster Effect,
Organometallics, 33 2014 6003-6012; DOI: 10.1021/om500620u
I.O. Koshevoy, Yuh-Chia Chang, Yi-An Chen, A.J. Karttunen, E.V. Grachova, S.P. Tunik, J. Jänis, T.A. Pakkanen and Pi-Tai Chou,
Luminescent gold(I) alkynyl clusters stabilized by flexible di-phosphine ligands,
Organometallics, 33(9) 2014 2363-2371; DOI: 10.1021/om5002952
Anna A. Melekhova, Dmitrii V. Krupenya, Vladislav V. Gurzhiy, Alexey S. Melnikov, Pavel Yu. Serdobintsev, Stanislav I. Selivanov and Sergey P. Tunik,
Synthesis, characterization, luminescence and non-linear optical properties of diimine platinum(II) complexes with arylacetylene ligands,
J. Organomet. Chem., 763-764 2014 1-5; DOI: 10.1016/j.jorganchem.2014.04.002
Dau Minh Thuy, J. R. Shakirova, A. J. Karttunen, E. V. Grachova, S. P. Tunik, A. S. Melnikov, T. A. Pakkanen and I. O. Koshevoy,
Coinage metal complexes supported by the tri- and tetraphosphine ligands,
Inorg. Chem., 53(9) 2014 4705-4715; DOI: 10.1021/ic500402m
J. R. Shakirova, E. V. Grachova, A. J. Karttunen, V. V. Gurzhiy, S. P. Tunik and I. O. Koshevoy,
Metallophilicity-assisted assembly of phosphine-based cage molecules,
Dalton Trans., 43 2014 6236-6243
Makarova A. A., Grachova E. V., Krupenya D. V., Vilkov O., Fedorov A., Usachov D., Generalov A., Koshevoy I. O., Tunik S. P., Rühl E., Laubschat C. and Vyalikh D. V.,
Insight into the Electronic Structure of the Supramolecular “Rods-in-Belt” AuI-CuI and AuI-AgI Self-Assembled Complexes from X-Ray Photoelectron and Absorption Spectroscopy,
J. Electron. Spectrosc. Relat. Phenom., 192 2014
26-34
I.
S. Krytchankou, D. V. Krupenya, A. J. Karttunen, S. P. Tunik, T. A. Pakkanen,
P.-T. Chou and I. O. Koshevoy, Triphosphine-supported bimetallic AuI-MI
(M = Ag, Cu) alkynyl clusters, Dalton Trans., 43 2014
3383-3394
Chelushkin
P. S., Krupenya D. V., Tseng Y.-J., Kuo T.-Y., Chou P.-T., Koshevoy I. O.,
Burov S. V., Tunik S. P., Water-Soluble Noncovalent Adducts of the
Heterometallic Copper Subgroup Complexes and Human Serum Albumin with
Remarkable Luminescent Properties, Chem. Commun. 2014 50 849-851
2013
Povolotskiy
A., Povolotckaia A., Petrov Y., Manshina A., Tunik S., Laser-induced
synthesis of metallic silver-gold nanoparticles encapsulated in carbon
nanospheres for surface-enhanced Raman spectroscopy and toxins detection, Appl.
Phys. Letters 2013 103(11) 113102:1-4.
Patel
J. Z., Parkkari T., Laitinen T., Kaczor A. A., Saario S. M., Savinainen J. R.,
Navia-Paldanius D., Cipriano M., Leppanen J., Koshevoy I. O., Poso A., Fowler
C. J., Laitinen J. T., Nevalainen T., Chiral 1,3,4-Oxadiazol-2-ones as Highly
Selective FAAH Inhibitors, J. Med. Chem. 2013 56(21)
8484-8496.
Krupenya
D. V., Snegurov P. A., Grachova E. V., Gurzhiy V. V., Tunik S. P., Melnikov A.
S., Serdobintsev P. Y., Vlakh E. G., Sinitsyna E. S., Tennikova T. B., New
Supramolecular AuI-CuI Complex as Potential Luminescent Label for Proteins,
Inorg. Chem. 2013 52(21) 12521-12528
Chang
Y.-C., Tang K.-C., Pan H.-A., Koshevoy I. O., Karttunen A. J., Chou P.-T., Harvesting
Fluorescence from Efficient Reverse Intersystem Crossing for Emissive Transition-Metal
Complexes, J. Phys. Chem. C 2013 117(40) 20494-20499
Dau T. M., Shakirova J. R., Domenech A.,
Janis J., Haukka M., Grachova
E. V., Pakkanen T. A., Tunik S. P., Koshevoy I. O., Ferrocenyl-Functionalized
Tetranuclear Gold(I) and Gold(I)-Copper(I) Complexes
Based on Tridentate Phosphanes, Eur. J. Inorg. Chem. 2013, 28, 4976-4983.
Pirinen S., Koshevoy I. O., Denifl P., Pakkanen T. T., A Single-Crystal Model for
MgCl2-Electron Donor Support Materials: [Mg3Cl5(THF)4Bu]2 (Bu = n-Butyl), Organometallics
2013, 32, (15), 4208-4213.
Shakirova J. R., Grachova E. V., Melnikov A. S., Gurzhiy V. V., Tunik S. P., Haukka
M., Pakkanen T. A., Koshevoy
I. O., Toward Luminescence Vapochromism of Tetranuclear
AuI-CuI Clusters, Organometallics 2013,
32, (15), 4061-4069.
Chang Y.-C., Tang K.-C., Pan H.-A.,
Liu S.-H., Koshevoy I. O., Karttunen
A. J., Hung W.-Y., Cheng M.-H., Chou P.-T., Harnessing fluorescence versus
phosphorescence branching ratio in (Phenyl)n bridged (n = 0-5) bimetallic Au(I)
complexes, J. Phys. Chem. C 2013, 117, (19), 9623-9632.
Makarova A. A., Grachova E.
V., Krupenya D. V., Vilkov
O., Fedorov A., Usachov D.,
Generalov A., Koshevoy I. O., Tunik
S. P., Ruehl E., Laubschat
C., Vyalikh D. V., Self-Assembled Supramolecular Complexes with
"Rods-in-Belt" Architecture in the Light of Soft X-rays, J. Phys. Chem. C 2013, 117, (23), 12385-12392.
Koshevoy I. O.,
Chang Y.-C., Karttunen A. J., Shakirova
J. R., Janis J., Haukka M., Pakkanen
T., Chou P.-T., Solid-State luminescence of Au-Cu-Alkynyl
complexes induced by metallophilicity-driven
aggregation, Chem. Eur. J. 2013, 19, (16), 5104-5112.
Krytchankou I. S., Krupenya D. V., Gurzhiy V. V., Belyaev A. A., Karttunen A. J.,
Koshevoy I. O., Melnikov A. S., Tunik S. P., Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane,
effect of the diphosphine ligand on luminescence
characteristics, J. Organomet. Chem. 2013,
723, 65-71.
Koshevoy I. O., Karttunen A. J., Kritchenkou I.
S., Krupenya D. V., Selivanov
S. I., Melnikov A. S., Tunik S. P., Haukka M., Pakkanen T. A., Sky-Blue Luminescent AuI-AgI
Alkynyl-Phosphine Clusters, Inorg. Chem. 2013, 52, (7),
3663-3673.
Dereza P. Y., Krytchankou
I. S., Krupenya D. V., Gurzhiy
V. V., Koshevoy I. O., Melnikov A. S., Tunik S. P., Synthesis, structural characterization, and
photophysical properties of AuI-CuI
heterometallic alkynyl
cluster complexes containing N-protected amino acid groups, Z. Anorg. Allg. Chem. 2013,
639, (2), 398-402.
2012
Smirnova E. S., Melekhova A. A., Gurzhiy V. V., Selivanov S. I., Krupenya D. V.,
Koshevoy I. O., Tunik S. P., Synthesis, structure, and photophysical
properties of the Di- and trinuclear phosphine-diimine complexes of copper(I), Z. Anorg. Allg. Chem. 2012,
638, (2), 415-422.
Shakirova J. R.,
Grachova E. V., Gurzhiy V. V., Koshevoy I. O.,
Melnikov A. S., Sizova O. V., Tunik
S. P., Laguna A., Luminescent heterometallic gold-copper alkynyl
complexes stabilized by tridentate phosphine, Dalton Trans. 2012, 41, (10), 2941-2949.
Shakirova J. R.,
Grachova E. V., Melekhova A. A., Krupenya
D. V., Gurzhiy V. V., Karttunen
A. J., Koshevoy I. O., Melnikov A. S., Tunik S. P., Luminescent AuI-CuI
triphosphane clusters that contain extended linear arylacetylenes, Eur.
J. Inorg. Chem. 2012, (25), 4048-4056.
Monakhov K. Y., Grachova E.
V., Starova G. L., Zessin
T., Linti G., The
solid-state, solution and gas-phase interactions of diphosphane
monooxide spacers with heavier group 8,9 transition
metals and gallium in novel organometallic assemblies: An experimental and
computational study, J. Organomet. Chem. 2012,
714, 22-31.
Manshina A. A., Povolotskiy A. V., Povolotskaya
A. V., Ivanova T. Y., Koshevoy I. O., Tunik S. P., Suvanto M., Pakkanen T. A., Laser-induced
heterometallic phase deposition from solutions of supramolecular complexes, Surf. Coat. Technol. 2012,
206, (16), 3454-3458.
Koshevoy I. O.,
Chang Y.-C., Karttunen A. J., Selivanov
S. I., Janis J., Haukka M., Pakkanen
T., Tunik S. P., Chou P.-T., Intensely luminescent homoleptic alkynyl decanuclear gold(I)
clusters and their cationic octanuclear phosphine derivatives, Inorg. Chem. 2012, 51, (13),
7392-7403.
Koshevoy I. O., Lin
C.-L., Hsieh C.-C., Karttunen A. J., Haukka M., Pakkanen T. A., Chou
P.-T., Synthesis, characterization and photophysical properties of PPh2-C2-(C6H4)n-C2-PPh2 based
bimetallic Au(i) complexes, Dalton Trans. 2012, 41,
(3), 937-945.
Koshevoy I. O.,
Chang Y.-C., Karttunen A. J., Haukka
M., Pakkanen T., Chou P.-T., Modulation of metallophilic bonds:
Solvent-induced isomerization and luminescence vapochromism of a polymorphic Au-Cu cluster, J. Am. Chem. Soc. 2012, 134, (15), 6564-6567.
Domenech-Carbo A., Koshevoy I.
O., Montoya N., Pakkanen T. A., Domenech-Carbo
M. T., Solvent-independent electrode
potentials of solids undergoing insertion electrochemical reactions: Part II.
Experimental data for alkynyl-diphosphine dinuclear Au(I) Complexes undergoing electron exchange
coupled to anion exchange, Journal of
Physical Chemistry C 2012, 116,
(49), 25984-25992.
Camara J., Crespo
O., Gimeno M. C., Koshevoy I. O., Laguna A., Ospino I., Smirnova E. S., Tunik S. P., Emission
tuning in dinuclear gold complexes with diphosphanes containing alkyne
and/or oligophenylene spacers, Dalton Trans. 2012, 41, (45), 13891-13898.
2011
Koshevoy I. O., Lin
C.-L., Karttunen A. J., Janis J., Haukka
M., Tunik S. P., Chou P.-T., Pakkanen
T. A., Stepwise 1D growth of luminescent
Au(I)-Ag(I) phosphine-alkynyl clusters: Synthesis, photophysical, and theoretical studies, Inorg. Chem. 2011, 50, (6), 2395-2403.
Koshevoy I. O., Lin
C.-L., Karttunen A. J., Haukka
M., Shih C.-W., Chou P.-T., Tunik S. P., Pakkanen T. A., Octanuclear gold(i) alkynyl-diphosphine clusters
showing thermochromic luminescence, Chem. Commun. 2011, 47, (19), 5533-5535.
Koshevoy I. O., Smirnova E. S., Haukka M., Laguna
A., Chueca J. C., Pakkanen
T. A., Tunik S. P., Ospino
I., Crespo O., Synthesis,
structural characterization, photophysical properties
and theoretical analysis of gold(I) thiolate-phosphine
complexes, Dalton Trans. 2011, 40, (28), 7412-7422.
Koshevoy I. O.,
Shakirova J. R., Melnikov A. S., Haukka M., Tunik S. P., Pakkanen T. A., Coinage metal complexes of
2-diphenylphosphino-3-methylindole, Dalton
Trans. 2011, 40, (31),
7927-7933.
Koshevoy I. O., Lin
C.-L., Karttunen A. J., Janis J., Haukka
M., Tunik S. P., Chou P.-T., Pakkanen
T. A., Highly luminescent octanuclear AuI-CuI clusters
adopting two structural motifs: The effect of aliphatic alkynyl
ligands, Chem. Eur. J. 2011, 17, (41), 11456-11466. ON COVER
Grachova E. V., Vologzhanina A. V., Smirnova E.
S., Tunik S. P., Synthesis
and crystal structure of Na4[Er2(EDTA)2(C2O4)] 8H2O (where EDTA stands for ethylenediamine-N,N-tetraacetate),
Russ. J. Inorg.
Chem. 2011, 56, (7), 1046-1049.
Domenech A., Koshevoy I.
O., Montoya N., Pakkanen T. A., Estimation of free energies of anion transfer from solid-state
electrochemistry of alkynyl-based Au(I) dinuclear and Au(I)-Cu(I) cluster complexes containing ferrocenyl groups, Electrochem. Commun. 2011, 13, (1), 96-98.
Domenech A., Koshevoy I.
O., Montoya N., Karttunen A. J., Pakkanen
T. A., Determination of individual gibbs energies of anion transfer and excess gibbs energies using an electrochemical method based on
insertion electrochemistry of solid compounds, J Chem Eng Data 2011, 56, (12), 4577-4586.
2010 - 2006
Ponomarenko V. I., Grachova E. V., Koshevoi I. O., Gindin V. A., Tunik S. P., Pursiainen I., Haukka M., Reaction of chiral
pyrrolylphosphine with polynuclear
carbonyl complexes of osmium and rhodium, Russ. J. Gen. Chem. 2010,
80, (3), 408-413.
Pennon D., Koshevoy
I. O., Estevan F., Sanau
M., Ubeda M. A., Perez-Prieto
J., Synthesis of a new C3-symmetric tripodal P4-tetradentate ligand and its application to the
formation of chiral metal complexes, Organometallics 2010, 29, (3), 703-706.
Koshevoy I. O., Lin
Y.-C., Chen Y.-C., Karttunen A. J., Haukka M., Chou P.-T., Tunik S.
P., Pakkanen T. A., Rational reductive fusion of two heterometallic
clusters: Formation of a highly stable, intensely phosphorescent Au-Ag
aggregate and application in two-photon imaging in human mesenchymal
stem cells, Chem. Commun.
2010, 46, (9), 1440-1442.
Koshevoy I. O., Karttunen A. J., Lin Y.-C., Lin C.-C., Chou P.-T., Tunik S. P., Haukka M., Pakkanen T. A., Synthesis,
photophysical and theoretical studies of luminescent
silver(i)-copper(i) alkynyl-diphosphine complexes, Dalton Trans. 2010, 39,
(9), 2395-2403.
Koshevoy I. O., Karttunen A. J., Tunik S. P.,
Janis J., Haukka M., Melnikov A. S., Serdobintsev P. Y., Pakkanen T.
A., Reversible protonation
of amine-functionalized luminescent Au-Cu clusters: Characterization, photophysical and theoretical studies, Dalton Trans. 2010, 39, (10), 2676-2683.
Koshevoy I. O., Koskinen L., Smirnova E. S., Haukka M., Pakkanen T. A.,
Melnikov A. S., Tunik S. P., Synthesis, structural characterization and luminescence studies of di- and trinuclear gold(I) alkynyl-phosphine complexes, Z. Anorg. Allg.
Chem. 2010, 636, (5), 795-802.
Koshevoy I. O., Ostrova P. V., Karttunen A. J.,
Melnikov A. S., Khodorkovskiy M. A., Haukka M., Janis J., Tunik S. P.,
Pakkanen T. A., Assembly
of the heterometallic Au(I)-M(I) (M = Cu, Ag)
clusters containing the dialkyne-derived diphosphines: Synthesis, luminescence and theoretical
studies, Dalton Trans. 2010, 39, (38), 9022-9031.
Koshevoy I. O., Karttunen A. J., Shakirova J. R., Melnikov A. S., Haukka M., Tunik S. P., Pakkanen T. A., Halide-directed
assembly of multicomponent systems: Highly ordered AuI-AgI molecular aggregates, Angew. Chem. Int. Ed. 2010,
49, (47), 8864-8866.
Koshevoy I. O., Haukka M., Selivanov S. I., Tunik S. P., Pakkanen T. A., Assembly of the Au-diphosphine
helical cage molecules via alkynyl-4-methylydine ligand transformation, Chem. Commun. 2010, 46, (47), 8926-8928.
Heaton B. T., Iggo J. A., Podkorytov I. S., Ponomarenko V. I., Selivanov S.
I., Tunik S. P., A
rare example of a di-cationic hydrido
carbonyl tetra-nuclear cluster, [H2Rh2Pt2(CO)7(PPh3)3]2+, Inorg. Chim. Acta 2010,
363, (3), 549-554.
Domenech A., Koshevoy I.
O., Montoya N., Pakkanen T. A., Electrochemical anion sensing using electrodes chemically modified with
Au(I)-Cu(I) heterotrimetallic alkynyl
cluster complexes containing ferrocenyl groups, Anal. Bioanal.
Chem. 2010, 397, (5), 2013-2022.
Bonet A., Gulyas
H., Koshevoy I. O., Estevan F., Sanau
M., Ubeda M. A., Fernandez E., Tandem beta-boration/arylation
of unsaturated carbonyl compounds by using a single palladium complex to catalyse both steps, Chem. Eur. J. 2010, 16,
(21), 6382-6390.
Serezhkin V. N., Vologzhanina A. V., Serezhkina L.
B., Smirnova E. S., Grachova E. V., Ostrova P. V., Antipin M. Y., Crystallochemical formula as a tool for describing
metal-ligand complexes - A pyridine-2,6-dicarb-oxylate example, Acta Crystallogr.
Sect. B Struct. Sci. 2009, 65, (1), 45-53.
Ponomarenko V. I., Krupenya D. V., Grachova E. V., Gindin
V. A., Selivanov S. I., Koshevoy I. O., Tunik S. P., Haukka M., Pursiainen J., Pirila P., Structure, stereochemistry and dynamics of tetranuclear polyhydride clusters
containing chiral heterobidentate
phosphanes, Z. Anorg.
Allg. Chem. 2009,
635, (15), 2515-2526.
Pakal'nis V. V., Sokolov A. Y., Slisenko A. A., Borovitov M. E., Tunik S. P., Sizova O. V., Synthesis
and spectral characteristics of a novel heterometallic
binuclear complex on the basis of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine, Russ. J. Gen. Chem. 2009, 79, (5), 980-984.
Lin Y.-C., Chou
P.-T., Koshevoy I. O., Pakkanen T. A., Studies of two-photon property of intensely
luminescent alkynyl-phosphine Gold(I)-Copper(I)
complexes, J Phys Chem
A 2009, 113, (33), 9270-9276.
Koshevoy I. O., Lin
Y.-C., Karttunen A. J., Chou P.-T., Vainiotalo P., Tunik S. P., Haukka M., Pakkanen T. A., Intensely luminescent alkynyl
- Phosphine Gold(l) - Copper(l) complexes: Synthesis,
characterization, photophysical, and computational
studies, Inorg. Chem. 2009, 48, (5), 2094-2102.
Koshevoy I. O., Karttunen A. J., Tunik S. P., Haukka M., Selivanov S. I.,
Melnikov A. S., Serdobintsev P. Y., Pakkanen T. A., Synthesis,
characterization, photophysical, and theoretical
studies of supramolecular gold(i)
- silver(i) alkynyl-phosphine
complexes, Organometallics 2009, 28, (5), 1369-1376.
Koshevoy I. O.,
Gutierrez-Puebla E., Lahuerta P., Monge
A., Ubeda M. A., Sanau M., Isolation of enantiomerically
pure organometallic palladium compounds: Synthesis of the triangles prepared
from enantiopure [cis-Pd2(C 6H4PPh2)2(NCCH3) 4]2+,
Dalton Trans. 2009, (16), 2993-2998.
Koshevoy I. O., Lin
Y.-C., Karttunen A. J., Haukka
M., Chou P.-T., Tunik S. P., Pakkanen
T. A., An intensely and oxygen
independent phosphorescent gold(i)-silver(i) complex: "trapping" an Au8Ag10 oligomer by two gold-alkynyl-diphosphine molecules, Chem. Commun. 2009, (20), 2860-2862.
Koshevoy I. O., Smirnova E. S., Domenech A., Karttunen A. J., Haukka M., Tunik S. P., Pakkanen T. A., Synthesis, electrochemical and theoretical
studies of the Au(i)-Cu(i) heterometallic clusters bearing ferrocenyl
groups, Dalton Trans. 2009, (39), 8392-8398.
Grachova E. V., Linti G., Protasova I. D., Tunik S. P., Bidentate phosphine oxides as ligands to form GaIII
shell complexes. [Ga(CH2(P(O)Ph)2)3]3+: Synthesis, structural and spectroscopic
study, Z. Anorg.
Allg. Chem. 2009,
635, (13-14), 2294-2296.
Penno D., Lillo V., Koshevoy I. O., Sanau M., Ubeda M. A., Lahuerta P., Fernandez E., Multifaceted palladium catalysts towards the tandem diboration-arylation
reactions of alkenes, Chem. Eur. J.
2008, 14, (34), 10648-10655.
Pakal'nis V. V., Borovitov M. E., Balova I. A., Tunik S. P., Ivanova N. V., Sizova O. V., Heteroligand bipyridyl-pyridylbenzimidazole Ru(II)
complexes. Synthesis, structural characterization, and investigation of
electronic structure, Russ. J. Gen.
Chem. 2008, 78, (8), 1594-1605.
Koshevoy I. O., Koskinen L., Haukka M., Tunik S. P., Serdobintsev P. Y.,
Melnikov A. S., Pakkanen T. A., Self-assembly of supramolecular luminescent AuI-CuI complexes: "Wrapping" an Au6Cu6 cluster
in a [Au3(diphosphine)3]3+ "Belt", Angew. Chem. Int. Ed. 2008, 47, (21), 3942-3945.
Koshevoy I. O., Karttunen A. J., Tunik S. P., Haukka M., Selivanov S. I.,
Melnikov A. S., Serdobintsev P. Y., Khodorkovskiy M. A., Pakkanen T.
A., Supramolecular luminescent gold(I)-copper(I) complexes:
Self-assembly of the AuxCuy clusters inside the [Au
3(diphosphine)3]3+ triangles, Inorg. Chem. 2008, 47, (20),
9478-9488.
Domenech A., Koshevoy I.
O., Penno D., Ubeda M. A., Electrochemical chiral
recognition by microparticle coatings of Pd complexes
with bridging cyclometalated phosphines,
Electrochim Acta 2008, 53, (8), 3416-3426.
Babij C., Farrar D. H., Poe A. J., Tunik S. P., Kinetic
study of the reaction of [Rh6(CO)16] with NO2-: Insertion of the nitrogen atom
into a Rh6 cluster core, Dalton
Trans. 2008, (43), 5922-5929.
Tomashevskaya M. M., Tunik S. P., Podkorytov I. S.,
Heaton B. T., Iggo J. A., Haukka
M., Pakkanen T. A., Pirila
P. L., Pursiainen J., A novel heterobidentate chiral
phosphine and its coordination chemistry in
transition metal clusters, J. Organomet. Chem. 2007,
692, (14), 2911-2923.
Moberg V., Haukka
M., Koshevoy I. O., Ortiz R., Nordlander E., Unprecedented enantioselectivity
in a cluster-based catalytic system, Organometallics
2007, 26, (17), 4090-4093.
Manshina A. A., Povolotskiy A. V., Ivanova T. Y.,
Tver'Yanovich Y. S., Tunik
S. P., Kim D., Kim M., Kwon S. C., Effect
of salt precursor on laser-assisted copper deposition, Appl Phys A 2007, 89, (3),
755-759.
Grachova E. V., Linti G., Stammler H.-G., Neumann
B., Tunik S. P., Wadepohl
H., Reactions of GaCp*
with a hemilabile derivative of Rh6(CO)16 - Synthesis
and structural characterization of two novel heterometallic
clusters: Rh6(CO)13(3-Ph2PC2H3), Eur.
J. Inorg. Chem. 2007, (1), 140-146.
Grachova E. V., Linti G., Reactivity
of InCp* towards transition metal carbonyl clusters:
Synthesis and structural characterization of the Rh6(CO)16-x(InCp*)x mixed-metal cluster compounds, x = 1-2, Eur. J. Inorg.
Chem. 2007, (22), 3561-3564.
Andreev I. A.,
Grachova E. V., Tunik S. P., Oparina
L. A., Sukhov B. G., Malysheva
S. F., Kinoshita I., Nishioka T., Structure and dynamic properties of
substituted carbonylhydride clusters H2RuOs3(CO)13
and H4Ru 4(CO)12 containing functionalized phosphines,
Russ. Chem. Bull. 2007, 56, (7), 1343-1350.
Ponomarenko V. I., Pilyugina T. S., Khripun V. D.,
Grachova E. V., Tunik S. P., Haukka
M., Pakkanen T. A., Reactions of diphenylpyridylphosphine with
H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and
isolation of the oxidative addition products, J. Organomet. Chem. 2006, 691, (1-2), 111-121.
Koshevoy I. O., Lahuerta P., Sanau M., Ubeda M. A., Domenech A., Dinuclear palladium(II) compounds with bridging cyclometalated phosphines.
Synthesis, crystal structure and electrochemical study, Dalton Trans. 2006, (46), 5536-5541.
Koshevoy I. O., Haukka M., Pakkanen T. A., Tunik S. P., Synthesis
of nonanuclear heterometallic
carbide clusters. Unexpected formation of the [Ru6(CO)16]2-[Pt 2(CO)2(dppm)2]2+ ion pair on the way to [Ru6C(CO)16Pt3(dppm)2], Dalton
Trans. 2006, (47), 5641-5647.
Grachova E. V., Krupenya D. V., Pilyugina T. S., Tunik S. P., Pursiainen J., Haukka M., Reactions
of carbonyl clusters with heterobidentate ligands.
Synthesis and structural characterization of H4Ru4(CO)10[k2(P,S)-Ph2P(2-CH3SC
6H4)] and Rh6(CO)14[k2(P,S)-Ph2P(2-CH3SC6H4)] clusters, Russ. J. Gen. Chem. 2006, 76, (5), 682-686.
Cotton F. A.,
Koshevoy I. O., Lahuerta P., Murillo C. A., Sanau M., Ubeda M. A., Zhao Q., High yield syntheses of stable, singly
bonded Pd26+ compounds, J. Am. Chem.
Soc. 2006, 128, (42),
13674-13675.
2005 - 2001
Trofimov B. A., Gusarova N. K., Sukhov B. G., Malysheva S. F., Tarasova O. A., Belogorlova N. A., Maximova M.
A., Tunik S. P., Atom-economic,
solvent-free, high yield synthesis of 2-(pyrrol-1-yl) propyldiorganylphosphines,
Synthesis 2005, (6), 965-970.
Koshevoy I. O., Haukka M., Pakkanen T. A., Tunik S. P., Vainiotalo P., Supermolecular assembly of tetra- And hexanuclear
carbonyl clusters using a novel polydentate pyridylphosphine ligand, Organometallics 2005,
24, (14), 3516-3526.
Koshevoy I. O., Sizova O. V., Tunik S. P., Lough A., Poe A. J., A
novel five-coordinate rhodium(I) complex, Eur. J. Inorg. Chem. 2005, (22), 4516-4520.
Grachova E. V., Jutzi P., Neumann B., Stammler
H.-G., Novel rhodium and ruthenium
carbonyl cluster complexes with face-and edge-bridging GaCp*
ligands. Synthesis and structural characterization of the Rh6(CO)12(GaCp*)4 and Ru6(CO)13(GaCp*)2(GaCp*) clusters, Dalton
Trans. 2005, (22), 3614-3616.
Baranovski V. I., Tunik S. P., Korolkov D. V., Quantum chemical study of the addition
effect on the geometry of the [Mo6S8(CN)6]6- cluster, Inorg. Chem. Commun. 2005, 8, (3), 242-245.
Babij C., Farrar D. H., Koshevoy I.
O., Poe A. J., Tunik S. P., Kinetic studies of some substituted hexarhodium
carbonyl clusters, Dalton Trans. 2005, (1), 116-122.
Tunik S. P., Pilyugina
T. S., Koshevoy I. O., Selivanov S. I., Haukka M., Pakkanen T. A., Reaction of (S)-BINAP with H4Ru4(CO)12. The
first example of face-bridging BINAP coordination and 100% stereoselectivity
in formation of a chiral tetranuclear
cluster framework, Organometallics
2004, 23, (3), 568-579.
Tunik S. P., Khripun
V. D., Haukka M., Pakkanen
T. A., Reactions of
2,4-hexadiyne-1,6-diol with [H2Os3(CO)9(PR3)] clusters. Cyclization
of the diyne and reversible exchange of the phosphine ligands between different positions of the
"Os3C3" framework, Dalton Trans.
2004, (11), 1775-1782.
Tunik S. P., The chemistry of carbonyl clusters of transition metals containing
labile and hemilabile ligands. Synthesis, reactivity,
and prospects for application, Russ.
Chem. Bull. 2004, 53, (12),
2657-2669.
Trofimov B. A., Sukhov B. G., Malysheva S. F., Belogorlova N. A., Arbuzova S.
N., Tunik S. P., Gusarova
N. K., Synthesis of tertiary bisphosphine oxides from methylacetylene
and secondary phosphine oxides, Russ. J. Org. Chem. 2004, 40, (1), 129-130.
Trofimov B. A., Sukhov B. G., Malysheva S. F., Belogorlova N. A., Tantsirev A.
P., Parshina L. N., Oparina
L. A., Tunik S. P., Gusarova
N. K., Addition of secondary phosphines to a vinyl ether of diacetone-d-glucose:
A new approach to optically active phosphines and
their derivatives, Tetrahedron Lett. 2004,
45, (49), 9143-9145.
Krupenya D. V., Selivanov S. I., Tunik S. P., Haukka M., Pakkanen T. A., The synthesis, structure and dynamic behaviour of disubstituted alkenylphosphine derivatives of [Rh6(CO)16], Dalton Trans. 2004, (16), 2541-2549.
Koshevoy I. O., Tunik S. P., Poe A. J., Lough A.,
Pursiainen J., Pirila P., A chiral bis(oxazoline) phosphine with a rigid backbone: Ligand synthesis and
characterization of products obtained in highly diastereoselective
reactions with a rhodium(I) complex and a tetrahedral "RhRu3" cluster,
Organometallics 2004, 23, (11), 2641-2650.
Koshevoy I. O.,
Grachova E. V., Tunik S. P., Haukka
M., Pakkanen T. A., Heaton B. T., Iggo
J. A., Podkorytov I. S., Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2]
and [Ru2Rh2Pt2(CO)12(dppni)2], Dalton Trans. 2004, (22), 3893-3899.
Heaton B. T., Iggo J. A., Podkorytov I. S., Tunik S. P., Application
of HMQC spectroscopy to the observation of the metal resonance in polymetallic compounds: The effect of multiple-metal spin
transitions, Magn. Reson. Chem.
2004, 42, (9), 769-775.
Babij C., Chen L., Koshevoy I. O.,
Poe A. J., QALE analysis of CO
dissociative kinetics of Ru(CO)4L (L = P-donor
ligands): Accelerating effects of hydrogen in PHnR3-n ligands (n = 1-2), Dalton Trans. 2004, (5), 833-838.
Tunik S. P., Koshevoy I. O., Poe A.
J., Farrar D. H., Nordlander E., Haukka'
M., Pakkanen T. A., Chiral hexarhodium carbonyl clusters containing heterobidentate phosphine ligands;
a structural and reactivity study, Dalton
Trans. 2003, (12), 2457-2467.
Tunik S. P., Khripoun
V. D., Balova I. A., Borovitov
M. E., Domnin I. N., Nordlander
E., Haukka M., Pakkanen T.
A., Farrar D. H., Reactions of
[H2Os3(CO)10] with conjugated diynes (RC2C2R)
containing nucleophilic oxygen in І position of
a substituent (R = Ph, І = CH2OH, C(O)Ph; R = І = CMe2(OH)), Organometallics 2003, 22, (17), 3455-3465.
Krupenya D. V., Danilov E. O., Rodgers M. A. J., Tunik
S. P., Reaction intermediates in the solution
photochemistry of a tetrarhodium carbonyl cluster:
FTIR structural characterization and transient kinetics, J Phys Chem A 2003, 107, (42), 8867-8871.
Grachova E. V., Haukka M., Heaton B. T., Nordlander
E., Pakkanen T. A., Podkorytov
I. S., Tunik S. P., The structure and dynamic behaviour of disubstituted derivatives of [Rh
6(CO) 16] containing heterobidentate bridging phosphine ligands, Dalton
Trans. 2003, (12), 2468-2473.
Farrar D. H.,
Grachova E. V., Haukka M., Heaton B. T., Iggo J. A., Pakkanen T. A., Podkorytov I. S., Tunik S. P., The structure and dynamic behaviour of disubstituted
derivatives of [Rh6(CO)16] containing bidentate
phosphorus ligands, Inorg. Chim. Acta 2003,
354, 11-20.
Tunik S. P., Balova
I. A., Borovitov M. E., Nordlander
E., Haukka M., Pakkanen T.
A., Unusual C-H bond activation - Aldol condensation of aromatic aldehydes
with the methyl group of a carbene-like triosmium cluster, J.
Chem. Soc. Dalton Trans. 2002,
(6), 827-828.
Koshevoy I. O., Tunik S. P., Jaaskelainen S., Haukka M., Pakkanen T. A., Podkorytov I. S., Synthesis
and structural characterization of mixed-metal Pt-Rh
clusters. Assembly of tetra- and tetra-hexanuclear
clusters from smaller metal fragments, J.
Chem. Soc. Dalton Trans. 2002,
(13), 2768-2774.
Grachova E. V., Jutzi P., Neumann B., Schebaum L.
O., Stammler H.-G., Tunik
S. P., Unusual selective substitution of
triply bridging carbonyl ligands for GaCp* in
Rh6(CO)16. Synthesis and structural characterization of the Rh6(CO)4 - x(GaCp*)x(CO)12 clusters, x = 1-4, J. Chem. Soc. Dalton Trans. 2002,
(3), 302-304.
Babij C., Browning C. S., Farrar D.
H., Koshevoy I. O., Podkorytov I. S., Poe A. J., Tunik S. P., Tripyrrolylphosphine
as a unique bridging ligand in the Rh6(CO)14(P(NC4H4)3 cluster: Structure,
bonding, fluxionality, thermodynamics, and kinetics
studies, J. Am. Chem. Soc. 2002, 124, (30), 8922-8931.
Tunik S. P., Khripun
V. D., Balova I. A., Nordlander
E., Haukka M., Pakkanen T.
A., Raithby P. R., Reactions of diacetylene ligands with trinuclear clusters. 3. Cyclization
of diynes with amino moieties on the metal core of
[H2Os3(CO)10], Organometallics 2001, 20, (18), 3854-3863.
Sizova O. V., Sizov
V. V., Tunik S. P., Quantum-chemical study of organophosphorus
ligands coordinated to chromium and nickel carbonyls, Russ. J. Gen. Chem. 2001,
71, (1), 50-57.
Koshevoy I. O., Tunik S. P., Jaaskelainen S., Haukka M., Pakkanen T. A., Linkage of heteronuclear
rhodium-platinum clusters, J. Chem.
Soc. Dalton Trans. 2001, (20),
2965-2967.
Kiriakidou-Kazemifar N. K., Haukka M., Pakkanen T. A., Tunik S. P., Nordlander E., Formation of rhodium carbonyl thiolate dimers via elimination
of dihydrogen; Crystal and molecular structure of
[Rh2(CO)4(SC6H4CH3)2], J. Organomet. Chem. 2001,
623, (1-2), 65-73.
Grachova E. V.,
Heaton B. T., Iggo J. A., Podkorytov
I. S., Smawfield D. J., Tunik
S. P., Whyman R., Stereochemical nonrigidity of
[Rh6 (CO)15L] clusters in solution, J.
Chem. Soc. Dalton Trans. 2001,
(22), 3303-3311.
Farrar D. H.,
Grachova E. V., Lough A., Patirana
C., Poe A. J., Tunik S. P., Ligand effects on the structures of Rh6(CO)15L clusters, J. Chem. Soc. Dalton Trans. 2001, (13), 2015-2019.
2000 - 1996
Heaton B. T., Iggo J. A., Podkorytov I. S., Smawfield D. J., Tunik S. P., Whyman R., Observation
of triple-quantum effects in the HMQC spectra of substituted derivatives of
Rh6(CO)16, Dalton Trans. 1999, (12), 1917-1919.
Dolgushin F. M., Grachova E.
V., Heaton B. T., Iggo J. A., Koshevoy I. O., Podkorytov I. S., Smawfield D.
J., Tunik S. P., Whyman R.,
Yanovskii A. I., Synthesis
and structural characterisation of the mixed metal
clusters [Rh2Pt3(CO)5(CO)4(PPh3)3] and [Rh2Pt2(CO)3-(CO)4(PPh3)3]; crystal
structure of [Rh2Pt3(CO)5(CO)4(PPh3)3], Dalton
Trans. 1999, (10), 1609-1614.
Tunik S. P., Podkorytov
I. S., Heaton B. T., Iggo J. A., Sampanthar
J., Multinuclear NMR studies on
substituted derivatives of Rh6(CO)16 in solution, J. Organomet. Chem. 1998, 550, (1-2), 221-231.
Tunik S. P., Grachova
E. V., Podkorytov I. S., Synthesis and Structure of the Carbonyl Nitrite Cluster
[Rh6(CO)13(Ph2PCH2PPh2)(NO2)]PPN, Russ.
J. Gen. Chem. 1998, 68, (10),
1674-1675.
Poe A. J., Tunik S. P., Dissociative
kinetics of 'lightly bonded ligands' L from the clusters Rh6(CO)15L (L= DMSO, NCMe, cyclooctene, THF and EtOH), Inorg. Chim. Acta 1998, 268, (2), 189-198.
Kuznetsov M. A., Kuchuk I. D., Tunik S. P., Photocatalytic Transformations of
Tetramethyl-4,5-diphenyl-4,5-bi-3H-pyrazolyl. Synthesis and Photolysis of the
First (1-Cyclopropenyl)pyrazole, Russ. J. Org. Chem. 1998, 34, (2), 245-249.
Tunik S. P., Grachova E. V., Denisov V. R., Starova G. L., Nikol'skii A. B., Dolgushin P.
M., Yanovsky A. I., Struchkov
Y. T., Reactions of diacetylene
ligands with trinuclear clusters II. Reactions of
hexa-2,4-diyne-1,6-diol and 1,4-diphenyl-1,3-butadiyne with Ru3(CO)12, J. Organomet.
Chem. 1997, 536-537, 339-343.
Tunik S. P., Vlasov
A. V., Krivykh V. V., Takats
J., Cooke J., Washington J., Acetonitrile-substituted
derivatives of Rh6(CO)16: Rh6(CO)16-x(NCMe) x (x = 1,
2), Inorganic Syntheses 1997, 239-244.
Tunik S. P., Shipil'
P. N., Vlasov A. V., Denisov
V. R., Nikols'kii A. B., Dolgushin
F. M., Yanovsky A. I., Struchkov
Y. T., Reactions of
(6-diphenylacetylene) chromiumtricarbonyl complexes
with polynuclear carbonyls. III. Reactions of
M4(CO)12 (M = Rh, Co) clusters with Cr(CO)3(PhC2Ph),
J. Organomet.
Chem. 1996, 515, (1-2), 11-17.
Before 1995
Karpov M. G., Tunik
S. P., Denisov V. R., Starova
G. L., Nikol'skii A. B., Dolgushin
F. M., Yanovsky A. I., Struchkov
Y. T., Reactions of diacetylene
ligands with trinuclear clusters. I Reactions of
2,4-hexadiyne-1,6-diol and its dicobalthexacarbonyl
derivatives with H2Os3(CO)10, J. Organomet. Chem. 1995,
485, (1-2), 219-225.
Tunik S. P., Pomogailo
S. I., Dzhardimalieva G. I., Pomogailo
A. D., Chuev I. I., Aldoshin
S. M., Nikol'skii A. B., Preparation and reactivity of metal-containing monomers - 29. Synthesis
and molecular structure of vinylpyridine derivatives
of Rh6(CO)16, Russ. Chem. Bull. 1994, 42, (5), 937-942.
Tunik S. P., Vlasov
A. V., Nikol'skii A. B., Starova
G. L., Ooi S., Nakai H.,
Sato T., Reactions of (diphenylacetylene)chromiumtricarbonyl
complexes with polynuclear carbonyls I. Synthesis of
Cr(CO)3(diphenylacetylene) complex and its reaction
with Co2(CO)8. Crystal and molecular structure of Cr(CO)3(diphenylacetylene
)Co2(CO)6, J. Organomet.
Chem. 1994, 464, (1), 71-76.
Tunik S. P., Vlasov
A. V., Kogdov K. V., Starova
G. L., Nikol'skii A. B., Manole
O. S., Struchkov Y. T., Synthesis and structural characterization of the isomers of Rh6(CO)14L2
clusters (L = NCME, Py, P(OPh)3),
X-ray crystal structure of trans-Rh6(CO)14{P(OPh3)}2, J. Organomet. Chem. 1994, 479, (1-2), 59-72.
Tunik S. P., Krym
V. R., Starova G. L., Nikol'skii
A. B., Podkorytov I. S., Ooi
S., Yamasaki M., Shiro M., Dark and photochemical reactions of Co3Rh(Co)12 with diphenylacetylene. Crystal and molecular structure of the
Co3Rh(CO)2(CO)8(PhC 2Ph) cluster, J. Organomet.
Chem. 1994, 481, (1), 83-88.
Tunik S. P., Yarmolenko
A. I., Nikol'skii A. B., Spectral characterization of intermediates in photochemical and dark
reactions of hexanuclear rhodium clusters, Inorg. Chim. Acta 1993,
205, (1), 71-77.
Tunik S. P., Osipov
M. V., Nikolskyi A. B., Synthesis and spectroscopic characterization of the heteronuclear
diphosphine linked cluster
Os3(CO)11(Ph2PCH2PPh2)Rh6(CO)15, J. Organomet. Chem. 1992,
426, (1), 105-107.
Tunik S. P., Vlasov
A. V., Gorshkov N. I., Starova
G. L., Nikol'skii A. B., Rybinskaya
M. I., Batsanov A. S., Struchkov
Y. T., Synthesis and characterization of
bis-(diphenylphosphinoethane)
-substituted hexarhodium clusters: Rh6(CO)14(L)2,
J. Organomet.
Chem. 1992, 433, (1-2), 189-201.
Tunik S. P., Vlasov
A. V., Nikol'skii A. B., Krivykh
V. V., Rybinskaya M. I., Photochemical synthesis of nitrile
derivatives of Rh6(CO)16, Russ Chem Bull 1989,
37, (12), 2600.
