St. Petersburg State University Department of Chemistry

Division of General and Inorganic Chemistry


Transition Metal Cluster Chemistry Group



Home Group Leader Group Members Research Interests/Current Projects Publications Teaching Partners

2019

E.V. Grachova, Design of Supramolecular Cluster Compounds of Copper Subgroup Metals Based on Polydentate Phosphine Ligands, Russ. J. Gen. Chem. Int. Ed., 89(6) (2019) 1102-1114; DOI: 10.1134/S1070363219060045 Themed issue dedicated to the 150th anniversary of Inorganic Chemistry Department of St. Petersburg State University

Aleksei A. Titov, Oleg A. Filippov, Alexander F. Smol’yakov, Ivan A. Godovikov, Julia R. Shakirova, Sergey P. Tunik, Ivan S. Podkorytov and Elena S. Shubina, Luminescent complexes of the trinuclear silver(I) and copper(I) pyrazolates supported with bis(diphenylphosphino)methane, Inorg. Chem., 58(13) (2019) 8645-8656; DOI: 10.1021/acs.inorgchem.9b00991

Ilya S. Kritchenkov, Julia R. Shakirova and Sergey P. Tunik, Efficient one-pot green synthesis of tetrakis(acetonitrile)copper(I) complex in aqueous media, RSC Adv., 9 (2019) 15531-15535; DOI: 10.1039/c8ra10564b

G. Chakkaradhari, T. Eskelinen, C. Degbe, A. Belyaev, A.S. Melnikov, E.V. Grachova, S.P. Tunik, P. Hirva, I.O. Koshevoy, Oligophosphine-thiocyanate copper(I) and silver(I) complexes and their borane derivatives showing delayed fluorescence, Inorg. Chem., 58(6) (2019) 3646-3660; DOI: 10.1021/acs.inorgchem.8b03166

K.S. Kisel, A.S. Melnikov, E.V. Grachova, A.J. Karttunen, A. Doménech-Carbó, K.Yu. Monakhov, V.G. Semenov, S.P. Tunik, I.O. Koshevoy, Supramolecular construction of cyanide-bridged ReI diimine multichromophores, Inorg. Chem., 58(3) (2019) 1988-2000; DOI: 10.1021/acs.inorgchem.8b02974

Anastasia I. Solomatina, Vadim A. Baigildin, Daniil D. Zhukovsky, Dmitrii V. Krupenya, Elena I. Koshel, Vladislav I. Shcheslavskiy, Sergey P. Tunik, Pavel S. Chelushkin, How to avoid protein aggregation to improve cellular uptake of albumin-based conjugates: towards the rational design of cell-penetrable phosphorescent probes, Colloid Polym. Sci., 297 (2019) 325-337; DOI: 10.1007/s00396-018-4412-x

Chelushkin P.S., Tunik S.P., Phosphorescence Lifetime Imaging (PLIM): State of the Art and Perspectives, In: Yamanouchi K., Tunik S., Makarov V., (eds) Progress in Photon Science. Recent Advances. Springer Series in Chemical Physics, Springer, Cham, 119 (2019) 109-128; DOI: 10.1007/978-3-030-05974-3_6

Anastasia I. Solomatina, Pavel S. Chelushkin, Tatiana O. Abakumova, Vladimir A. Zhemkov, Mee-Whi Kim, Ilya Bezprozvanny, Vladislav V. Gurzhiy, Alexey S. Melnikov, Yuri A. Anufrikov, Igor O. Koshevoy, Shih-Hao Su, Pi-Tai Chou, Sergey P. Tunik, Reactions of Cyclometalated Platinum(II) [Pt(N^C)(PR3)Cl] Complexes with Imidazole and Imidazole-Conjugated Biomolecules: Fine-Tuning Reactivity and Photophysical Properties via Ligand Design, Inorg. Chem., 58 (2019) 204-217; DOI: 10.1021/acs.inorgchem.8b02204


2018

V.V. Khistiaeva, A.S. Melnikov, S.O. Slavova, V.V. Sizov, G.L. Starova, I.O. Koshevoy, and E.V. Grachova, Heteroleptic β-diketonate Ln(III) complexes decorated by pyridyl substituted pyridazine ligand: synthesis, structure and luminescent properties, Inorg. Chem. Front., 5 (2018) 3015-3027; DOI: 10.1039/C8QI00712H ON COVER

M.A. Zhukovskaya, D.D. Zhukovsky, V.V. Pavlovskiy, V.V. Porsev, R.A. Evarestov, S.P. Tunik, Binuclear platinum(II) complexes based on a new bis-bidentate 3,6-di(thien-2-yl)pyridazine skeleton, a novel type of deep-red phosphorescent emitters: Synthesis and non-empirical calculations, Inorg. Chem. Commun., 98 (2018) 105-110; DOI: 10.1016/j.inoche.2018.10.002

Julia R. Shakirova, Elena V. Grachova, Vladislav V. Gurzhiy, Senthil Kumar Thangaraj, Janne Jänis, Alexey S. Melnikov, Antti J. Karttunen, Sergey P. Tunik, Igor O. Koshevoy, Heterometallic cluster-capped tetrahedral assemblies with postsynthetic modification of the metal cores, Angew. Chem. Int. Ed., 57 (2018) 14154-14158; DOI: 10.1002/anie.201809058

Ilya S. Kritchenkov, Anastasia Yu. Gitlina, Igor O. Koshevoy, Alexey S. Melnikov, and Sergey P. Tunik, Luminescent Silver-Copper ‘Hourglass’ Hepta- and Decanuclear Alkynyl-Phosphine Clusters, Eur. J. Inorg. Chem., 34 (2018) 3822-3828; DOI: 10.1002/ejic.201800631

I.O. Koshevoy, V. Sivchik, Rajib Sarker, Zong-Ying Liu, Kun-You Chung, E.V. Grachova, A.J. Karttunen, and Pi-Tai Chou, Improvement of the photophysical performance of platinum cyclometalated complexes in halogen bonded adducts, Chem. Eur. J., 24 (2018) 11475-11484; DOI: 10.1002/chem.201802182

Julia R. Shakirova, Olesya A. Tomashenko, Ekaterina E. Galenko, Alexander F. Khlebnikov, Pipsa Hirva, Galina L. Starova, Shih-Hao Su, Pi-Tai Chou, Sergey P. Tunik, Metalated Ir(III) complexes based on a luminescent diimine ligands; synthesis and photophysical study, Inorg. Chem., 57 (2018) 6853-6864; DOI: 10.1021/acs.inorgchem.8b00390

K.S. Kisel, T. Eskelinen, W. Zafar, A.I. Solomatina, P. Hirva, E.V. Grachova, S.P. Tunik, I.O. Koshevoy, Chromophore-functionalized phenanthro-diimine ligands and their Re(I) complexes, Inorg. Chem., 57 (2018) 6349-6361; DOI: 10.1021/acs.inorgchem.8b00422

A.Yu. Gitlina, M.V. Ivonina, V.V. Sizov, G.L. Starova, A.P. Pushkarev, D. Volyniuk, S.P. Tunik, I.O. Koshevoy and E.V. Grachova, The rare example of compact heteroleptic cyclometalated iridium(III) complex demonstrating well-separated dual emission, Dalton Trans., 47 (2018) 7578-7586; DOI: 10.1039/C8DT01336E

A.I. Solomatina, Shih-Hao Su, M.M. Lukina, V.V. Dudenkova, V.I. Shcheslavskiy, Cheng-Ham Wu, P.S. Chelushkin, Pi-Tai Chou, I.O. Koshevoy and S.P. Tunik, Water-soluble cyclometalated platinum(II) and iridium(III) complexes: synthesis, tuning of the photophysical properties, and in vitro and in vivo phosphorescence lifetime imaging, RSC Adv., 8 (2018) 17224-17236; DOI: 10.1039/c8ra02742k

D.D. Zhukovsky, V.V. Sizov, G.L. Starova, S.P. Tunik, and E.V. Grachova, Binuclear luminescent Pt(II) complexes based on substituted 3,6-diphenylpyridazines; synthesis and photophysical study, J. Organomet. Chem., 867 (2018) 367-374; DOI: 10.1016/j.jorganchem.2017.12.023

K. Keller, A.V. Yakovlev, E.V. Grachova, and A.V. Vinogradov, Inkjet Printing of Multicolor Daylight Visible Opal Holography, Adv. Funct. Mater., (2018) 1706903; DOI: 10.1002/adfm.201706903

N. Glebko, Thuy Minh Dau, A.S. Melnikov, E.V. Grachova, I.V. Solovyev, A. Belyaev, A.J. Karttunen and I.O. Koshevoy, Luminescence thermochromism of gold(I) phosphane-iodide complexes: a rule or an exception?, Chem. Eur. J., 24 (2018) 3021-3029; DOI: 10.1002/chem.201705544

Julia R. Shakirova, Masaki Shimada, Dmitrii A. Olisov, Galina L. Starova, Hiroshi Nishihara, Sergey P. Tunik, Dinuclear Diphosphine Complexes of Gold(I) Alkynyls, the Effects of Alkynyl Substituents onto Photophysical Behavior, Z. Anorg. Allg. Chem., (2018) 308-316; DOI: 10.1002/zaac.201700415

I.V. Solovyev, A. Kondinski, K.Yu. Monakhov, I.O. Koshevoy and E.V. Grachova, Synthesis, photophysical properties and cation-binding studies of bipyridine-functionalized gold(I) complexes, Inorg. Chem. Front., 5 (2018) 160-171; DOI: 10.1039/C7QI00514H

I.O. Koshevoy, A. Belyaev, T. Eskelinen, Thuy Minh Dau, Y.Yu. Ershova, A.S. Melnikov, S.P. Tunik, and P. Hirva, Cyanide-assembled d10 coordination polymers and cycles: excited state metallophilic modulation of solid-state luminescence, Chem. Eur. J., 24 (2018) 1404-1415; DOI: 10.1002/chem.201704642


2017

Alexander A. Penney, Galina L. Starova, Elena V. Grachova, Vladimir V. Sizov, Mikhail A. Kinzhalov, and Sergey P. Tunik, Gold(I) Alkynyls Supported by Mono- and Bidentate NHC Ligands: Luminescence and Isolation of Unprecedented Ionic Complexes, Inorg. Chem., 56 (2017) 14771-14787; DOI: 10.1021/acs.inorgchem.7b01508

A. Belyaev, Yi-Ting Chen, Shih-Hao Su, Yu-Jui Tseng, A.J. Karttunen, S.P. Tunik, Pi-Tai Chou, I.O. Koshevoy, The P-heterocyclic fluorophores, obtained via Cu(II)-mediated cyclization, are suitable for cell imaging due to their stability, water solubility and low toxicity, Chem. Commun., 53 (2017) 10954-10957; DOI: 10.1039/C7CC06882D

Tunik S., Chelushkin P., Koshevoy I., Photophysical Properties of Triplet Emitters Based on Au-Cu, Au-Ag Supramolecular Complexes and Prospective of Application in Sensing, Bioimaging, and OLEDs, In: Yamanouchi K. (eds) Progress in Photon Science. Springer Series in Chemical Physics, Springer, Cham 115 (2017) 109-123; DOI: 10.1007/978-3-319-52431-3_10

Julia R. Shakirova, Olesya A. Tomashenko, Elena V. Grachova, Galina L. Starova, Vladimir V. Sizov, Alexander F. Khlebnikov and Sergey P. Tunik, Gold(I)-alkynyl complexes with a new type N-donor heterocyclic ligand: Synthesis and photophysical properties, Eur. J. Inorg. Chem., 36 (2017) 4180-4186; DOI: 10.1002/ejic.201700731

K.S. Kisel, A.S. Melnikov, E.V. Grachova, P. Hirva, S.P. Tunik, I.O. Koshevoy, Linking Re(I) and Pt(II) chromophores with aminopyridines: a simple route to achieve a complicated photophysical behavior, Chem. Eur. J., 23 (2017) 11301-11311; DOI: 10.1002/chem.201701539

A.I. Solomatina, I.O. Aleksandrova, A.J. Karttunen, S.P. Tunik, I.O. Koshevoy, Dibenzothiophene-platinated complexes: probing the effect of ancillary ligands on the photophysical performance, Dalton Trans., 46 (2017) 3895-3905; DOI: 10.1039/C7DT00349H

J.R. Shakirova, E.V. Grachova, V.V. Sizov, G.L. Starova, I.O. Koshevoy, A.S. Melnikov, M.C. Gimeno, A. Laguna, and S.P. Tunik, Polynuclear cage-like Au(I) phosphane complexes based on S2− template; observation of multiple luminescence in coordinated polyaromatic systems, Dalton Trans., 46 (2017) 2516-2523; DOI: 10.1039/C6DT04126D

E.G. Vlakh, E.V. Grachova, D.D. Zhukovsky, A.V. Hubina, J.R. Shakirova, A.S. Mikhailova, V.V. Sharoyko, S.P. Tunik, T.B. Tennikova, Self-assemble nanoparticles based on polypeptides containing C-terminal luminescent Pt-cysteine complex, Sci. Rep., (2017) 7:41991; DOI: 10.1038/srep41991

Yi-Ting Chen, I.S. Krytchankou, A.J. Karttunen, E.V. Grachova, S.P. Tunik, Pi-Tai Chou, and I.O. Koshevoy, Silver Alkynyl-Phosphine Clusters: an Electronic Effect of the Alkynes Defines Structural Diversity, Organometallics, 36 (2017) 480-489; DOI: 10.1021/acs.organomet.6b00866

A.I. Solomatina, P.S. Chelushkin, D.V. Krupenya, I.S. Podkorytov, T.O. Artamonova, V.V. Sizov, A.S. Melnikov, V.V. Gurzhiy, E.I. Koshel, V.I. Shcheslavskiy, S.P. Tunik, Coordination to Imidazole Ring Switches On Phosphorescence of Platinum Cyclometalated Complexes: The Route to Selective Labeling of Peptides and Proteins via Histidine Residues, Bioconjugate Chem., 28 (2017) 426-437; DOI: 10.1021/acs.bioconjchem.6b00598

S. Schlicht, A. Kireev, E. Grachova, S. Tunik, A. Manshina, J. Bachmann, A model electrode of well-defined geometry prepared by direct laser-induced decoration of nanoporous templates with Au-Ag@C nanoparticles, Nanotechnology, 28 (2017) 065405; DOI: 10.1088/1361-6528/aa536a

E.I. Koshel, P.S. Chelushkin, A.S. Melnikov, P.Yu. Serdobintsev, A.Yu. Stolbovaia, A.F. Saifitdinova, V.I. Shcheslavskiy, O. Chernyavskiy, E.R. Gaginskaya, I.O. Koshevoy, S.P. Tunik, Lipophilic phosphorescent gold(I) clusters as selective probes for visualization of lipid droplets by two-photon microscopy, J. Photoch. Photobio. A, 332 (2017) 122-130; DOI: 10.1016/j.jphotochem.2016.08.017


2016

Bashouti M.Y., Povolotckaia A.V., Povolotskiy A.V., Tunik S.P., Christiansen S.H., Leuchs G., Manshina A.A., Spatially-controlled laser-induced decoration of 2D and 3D substrates with plasmonic nanoparticles, RSC Advances, 6 (2016) 75681-75685; DOI: 10.1039/C6RA16585K

I. Strelnik, E. Musina, E. Grachova, A. Karasik, and O. Sinyashin, Luminescent copper(I) and gold(I) complexes of 1,5-diaza-3,7-diphosphacyclooctanes, Phosphrous, Sulfur, and Silicon, 191 (2016) 1518-1519; DOI: 10.1080/10426507.2016.1212346

Andrey Belyaev, Thuy Minh Dau, Janne Jänis, Elena V. Grachova, Sergey P. Tunik and Igor O. Koshevoy, Low-nuclearity alkynyl d10 clusters supported by chelating multidentate phosphines, Organometallics, 35 (2016) 3763-3774; DOI: 10.1021/acs.organomet.6b00701

R.R. Ramazanov, A.I. Kononov, A.M. Nesterenko, J.R. Shakirova, E.V. Grachova, I.O. Koshevoy and S.P. Tunik, Luminescence Switching of an Au-Cu Supramolecular Complex: a Physical Insight, J. Phys. Chem. C, 120 (2016) 25541-25547; DOI: 10.1021/acs.jpcc.6b08710

Ekaterina E. Galenko, Alexey V. Galenko, Alexander F. Khlebnikov, Mikhail S. Novikov, and Julia R. Shakirova, Synthesis and intramolecular azo coupling of 4-diazopyrrole-2-carboxylates: selective approach to benzo and hetero [c]-fused 6H-pyrrolo[3,4-c]pyridazine-5-carboxylates, J. Org. Chem., 81 (2016) 8495-8507; DOI: 10.1021/acs.joc.6b01662

I.D. Strelnik, V.V. Gurzhiy, V.V. Sizov, E.I. Musina, A.A. Karasik, S.P. Tunik, and E.V. Grachova, A stimuli-responsive Au(I) complex based on aminomethylphosphine template: synthesis, crystalline phases and luminescent properties, CrystEngComm, 18 (2016) 7629–7635; DOI: 10.1039/C6CE01272H

Thuy Minh Dau, Benjamin Darko Asamoah, A. Belyaev, Gomathy Chakkaradhari, P. Hirva, J. Jänis, E.V. Grachova, S.P. Tunik and I.O. Koshevoy, Adjustable coordination of a hybrid phosphine-phosphine oxide ligand in luminescent Cu, Ag and Au complexes, Dalton Trans., 45 (2016) 14160-14173; DOI: 10.1039/c6dt02435a

A.A. Penney, V.V. Sizov, E.V. Grachova, D.V. Krupenya, V.V. Gurzhiy, G.L. Starova and S.P. Tunik, Aurophilicity in Action: Fine-tuning the Gold(I)–Gold(I) Distance in the Excited State to Modulate the Emission in a Series of Dinuclear Homoleptic Gold(I)–NHC complexes, Inorg. Chem., 55(10) (2016) 4720-4732; DOI: 10.1021/acs.inorgchem.5b02722 ON COVER

I. Kondrasenko, Kun-you Chung, Yi-Ting Chen, J. Koivistoinen, E.V. Grachova, A.J. Karttunen, Pi-Tai Chou and I.O. Koshevoy, Harnessing fluorescence versus phosphorescence ratio via ancillary ligand fine-tuned MLCT contribution, J. Phys. Chem. C, 120(22) (2016) 12196-12206; DOI: 10.1021/acs.jpcc.6b03064

A.A. Makarova, E.V. Grachova, D. Niedzialek, A.I. Solomatina, S. Sonntag, A.V. Fedorov, O.Yu. Vilkov, V.S. Neudachina, C. Laubschat, S.P. Tunik, and D.V. Vyalikh, A curious interplay in the films of N-heterocyclic carbene PtII complexes upon deposition of alkali metals, Sci. Rep., (2016) 6:25548; DOI: 0.1038/srep25548

V. Fernández-Moreira, J. Cámara, E.S. Smirnova, I.O. Koshevoy, A. Laguna, S.P. Tunik, M.C. Blanco, M.C. Gimeno, Tuning the energy emission from violet to yellow with bidentate phosphine gold(III) complexes, Organometallics, 35 (2016) 1141-1150; DOI: 10.1021/acs.organomet.6b00135

V. Sivchik, E.V. Grachova, A.S. Melnikov, S.N. Smirnov, A.Yu. Ivanov, S.P. Tunik and I.O. Koshevoy, Solid state and solution metallophilic aggregation of a cationic [Pt(NCN)]+ cyclometalated complex, Inorg. Chem., 55(7) (2016) 3351-3363; DOI: 10.1021/acs.inorgchem.5b02713

Gomathy Chakkaradhari, Yi-Ting Chen, A.J. Karttunen, Minh Thuy Dau, J. Jänis, S.P. Tunik, Pi-Tai Chou, Mei-Lin Ho and I.O. Koshevoy, Luminescent Triphosphine Cyanide d10 Metal Complexes, Inorg. Chem., 55(5) (2016) 2174-2184; DOI: 10.1021/acs.inorgchem.5b02581

E.I. Musina, A.V. Shamsieva, I.D. Strelnik, T.P. Gerasimova, D.B. Krivolapov, I.E. Kolesnikov, E.V. Grachova, S.P. Tunik, C. Bannwarth, S. Grimme, S.A. Katsyuba, A.A. Karasik and O.G.Sinyashin, Synthesis of novel pyridyl containing phospholanes and their polynuclear luminescent copper(I) complexes, Dalton Trans., 45 (2016) 2250-2260; DOI: 10.1039/C5DT03346B

Koshel E.I., Tomashenko O.A., Khlebnikov A.F., Gaginskaya E.R., Saifitdinova A.F., and Tunik S.P., A new nuclear heterocyclic fluorescent dye – a promising tool for karyology and cytogenetics, Chromosome Res., 24(suppl 1) (2016) 29; DOI: 10.1007/s10577-016-9532-x

A.A. Beljaev, D.V. Krupenya, E.V. Grachova, V.V. Gurzhiy, A.S. Melnikov, P.Yu. Serdobintsev, E.S. Sinitsyna, E.G. Vlakh, T.B. Tennikova and S.P. Tunik, Supramolecular AuI-CuI complexes as new luminescent labels for covalent bioconjugation, Bioconjugate Chem., 27(1) (2016) 143-150; DOI: 10.1021/acs.bioconjchem.5b00563 ON COVER


2015

V.V. Sivchik, A.I. Solomatina, Yi-Ting Chen, A.J. Karttunen, S.P. Tunik, Pi-Tai Chou and I.O. Koshevoy, Halogen bond as luminescence amplifier: a case study using platinum cyclometalated complex as a paradigm, Angew. Chem. Int. Ed., 54(47) (2015) 14057-14060; DOI: 10.1002/anie.201507229

Olesya A. Tomashenko, Alexander F. Khlebnikov, Ivan P. Mosiagin, Mikhail S. Novikov, Elena V. Grachova, Julia R. Shakirova and Sergey P. Tunik, A new heterocyclic skeleton with highly tunable absorbtion/emission wavelength via H-bonding, RCS Adv., 5 (2015) 94551-94561; DOI: 10.1039/C5RA17755C

B.T. Heaton, E.V. Grachova, S.P. Tunik and I.S. Podkorytov, Comment on “The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]” by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D, Dalton Trans., 44 (2015) 16611-16613; DOI: 10.1039/C5DT01099C

Ilya S. Krytchankou, Igor O. Koshevoy, Vladislav V. Gurzhiy, Vladimir A. Pomogaev, Sergey P. Tunik, Luminescence solvato- and vapochromism of alkynyl-phosphine copper clusters, Inorg. Chem., 54 2015 8288-8297; DOI: 10.1021/acs.inorgchem.5b00239

A. Manshina, A. Povolotskiy, A. Povolotckaia, A. Kireev, Yu. Petrov, S. Tunik, Annealing effect: Controlled modification of the structure, composition and plasmon resonance of hybrid Au-Ag/C nanostructures, Appl. Surf. Sci., 353 2015 11-16; DOI: 10.1016/j.apsusc.2015.06.048

Gomathy Chakkaradhari, Andrey A. Belyaev, Antti. J. Karttunen, Vasily Sivchik, Sergey P. Tunik and Igor O. Koshevoy, Alkynyl triphosphine copper complexes: synthesis and photophysical studies, Dalton Trans., 44 2015 13294-13304; DOI: 10.1039/C5DT01870F

A.A. Manshina, E.V. Grachova, A.V. Povolotskiy, A.V. Povolotckaia, Yu.V. Petrov, I.O. Koshevoy, A.A. Makarova, D.V. Vyalikh, and S.P. Tunik, Laser-induced transformation of supramolecular complexes: a novel approach to control formation of hybrid multi-yolk-shell Au-Ag@a-C:H nanostructures for stable SERS substrates, Sci. Rep., 2015 5:12027; DOI: 10.1038/srep12027

P.S. Chelushkin, N.V. Nukolova, A.S. Melnikov, P.Yu. Serdobintsev, P.A. Melnikov, D.V. Krupenya, I.O. Koshevoy, S.V. Burov, and S.P. Tunik, HSA-based Phosphorescent Probe for Two-Photon in vitro Visualization, J. Inorg. Biochem., 149 2015 108-111; DOI: 10.1016/j.jinorgbio.2015.03.014

M. Y. Bashouti, A. Manshina, A. Povolotckaia, A. Povolotskiy, A. Kireev, Y. Petrov, M. Mačković, E. Spiecker, I. Koshevoy, S. Tunik and S. Christiansen, Direct laser writing of μ-chips based on hybrid C–Au–Ag nanoparticles for express analysis of hazardous and biological substances, Lab on a Chip, 15 2015 1742-1747; DOI: 10.1039/c4lc01376j

K.S. Kisel, G.Linti, G.L. Starova, V.V. Sizov, A.S. Melnikov, A.P. Pushkarev, M.N. Bochkarev, E.V. Grachova and S.P. Tunik, Synthesis, structure and photophysical properties of Eu and Lu diketonates with neutral polydentate imidazolyl-methanamine ligand, Eur. J. Inorg. Chem., 10 2015 1734-1743; DOI: 10.1002/ejic.201403186

A. A. Makarova, E. V. Grachova, V. S. Neudachina, L. V. Yashina, A. Blüher, S. L. Molodtsov, M. Mertig, H. Ehrlich, V. K. Adamchuk, C. Laubschat and D. V. Vyalikh, Insight into bio-metal interface formation in vacuo: Interplay of S-layer protein with copper and iron, Sci. Rep., 2015 5:8710; DOI: 10.1038/srep08710

Ilya Kondrasenko, Kristina S. Kisel, Antti J. Karttunen, Janne Jänis, Elena V. Grachova, Sergey P. Tunik and Igor O. Koshevoy, Rhenium(I) complexes with alkynyl-phosphine ligands: structural, photophysical and theoretical studies, Eur. J. Inorg. Chem., 5 2015 864-875; DOI: 10.1002/ejic.201403053

A.I. Solomatina, D.V. Krupenya, V.V. Gurzhiy, I. Zlatkin, A.P. Pushkarev, M.N. Bochkarev, N.A. Besley, E. Bichoutskaia, S.P. Tunik, Cyclometallated platinum(II) complexes containing NHC ligands; synthesis, characterization, photophysics and their application as emitters in OLEDs, Dalton Trans., 44 2015 7152-7162; DOI: 10.1039/C4DT03106G ON COVER


2014

Thuy Minh Dau, Yi-An Chen, A.J. Karttunen, E.V. Grachova, S.P. Tunik, Ke-Ting Lin, Wen-Yi Hung, Pi-Tai Chou, T.A. Pakkanen and I.O. Koshevoy, Tetragold(I) complexes: solution isomerization and tunable solid-state luminescence, Inorg. Chem., 53(24) 2014 12720-12731; DOI: 10.1021/ic501470v

Anna Lähde, Igor Koshevoy, Tommi Karhunen, Tiina Torvela, Tapani A. Pakkanen, Jorma Jokiniemi, Aerosol-assisted synthesis of gold nanoparticles, J. Nanopart. Res., 2014 16:2716 DOI: 10.1007/s11051-014-2716-4

Leonid V. Romashov, Levon L. Khemchyan, Evgeniy G. Gordeev, Igor O. Koshevoy, Sergey P. Tunik, and Valentine P. Ananikov, Design of a Bimetallic Au/Ag System for Dechlorination of Organochlorides: Experimental and Theoretical Evidence for the Role of the Cluster Effect, Organometallics, 33 2014 6003-6012; DOI: 10.1021/om500620u

I.O. Koshevoy, Yuh-Chia Chang, Yi-An Chen, A.J. Karttunen, E.V. Grachova, S.P. Tunik, J. Jänis, T.A. Pakkanen and Pi-Tai Chou, Luminescent gold(I) alkynyl clusters stabilized by flexible di-phosphine ligands, Organometallics, 33(9) 2014 2363-2371; DOI: 10.1021/om5002952

Anna A. Melekhova, Dmitrii V. Krupenya, Vladislav V. Gurzhiy, Alexey S. Melnikov, Pavel Yu. Serdobintsev, Stanislav I. Selivanov and Sergey P. Tunik, Synthesis, characterization, luminescence and non-linear optical properties of diimine platinum(II) complexes with arylacetylene ligands, J. Organomet. Chem., 763-764 2014 1-5; DOI: 10.1016/j.jorganchem.2014.04.002

Dau Minh Thuy, J. R. Shakirova, A. J. Karttunen, E. V. Grachova, S. P. Tunik, A. S. Melnikov, T. A. Pakkanen and I. O. Koshevoy, Coinage metal complexes supported by the tri- and tetraphosphine ligands, Inorg. Chem., 53(9) 2014 4705-4715; DOI: 10.1021/ic500402m

J. R. Shakirova, E. V. Grachova, A. J. Karttunen, V. V. Gurzhiy, S. P. Tunik and I. O. Koshevoy, Metallophilicity-assisted assembly of phosphine-based cage molecules, Dalton Trans., 43 2014 6236-6243

Makarova A. A., Grachova E. V., Krupenya D. V., Vilkov O., Fedorov A., Usachov D., Generalov A., Koshevoy I. O., Tunik S. P., Rühl E., Laubschat C. and Vyalikh D. V., Insight into the Electronic Structure of the Supramolecular “Rods-in-Belt” AuI-CuI and AuI-AgI Self-Assembled Complexes from X-Ray Photoelectron and Absorption Spectroscopy, J. Electron. Spectrosc. Relat. Phenom., 192 2014 26-34

I. S. Krytchankou, D. V. Krupenya, A. J. Karttunen, S. P. Tunik, T. A. Pakkanen, P.-T. Chou and I. O. Koshevoy, Triphosphine-supported bimetallic AuI-MI (M = Ag, Cu) alkynyl clusters, Dalton Trans., 43 2014 3383-3394

Chelushkin P. S., Krupenya D. V., Tseng Y.-J., Kuo T.-Y., Chou P.-T., Koshevoy I. O., Burov S. V., Tunik S. P., Water-Soluble Noncovalent Adducts of the Heterometallic Copper Subgroup Complexes and Human Serum Albumin with Remarkable Luminescent Properties, Chem. Commun. 2014 50 849-851


2013

Povolotskiy A., Povolotckaia A., Petrov Y., Manshina A., Tunik S., Laser-induced synthesis of metallic silver-gold nanoparticles encapsulated in carbon nanospheres for surface-enhanced Raman spectroscopy and toxins detection, Appl. Phys. Letters 2013 103(11) 113102:1-4.

Patel J. Z., Parkkari T., Laitinen T., Kaczor A. A., Saario S. M., Savinainen J. R., Navia-Paldanius D., Cipriano M., Leppanen J., Koshevoy I. O., Poso A., Fowler C. J., Laitinen J. T., Nevalainen T., Chiral 1,3,4-Oxadiazol-2-ones as Highly Selective FAAH Inhibitors, J. Med. Chem. 2013 56(21) 8484-8496.

Krupenya D. V., Snegurov P. A., Grachova E. V., Gurzhiy V. V., Tunik S. P., Melnikov A. S., Serdobintsev P. Y., Vlakh E. G., Sinitsyna E. S., Tennikova T. B., New Supramolecular AuI-CuI Complex as Potential Luminescent Label for Proteins, Inorg. Chem. 2013 52(21) 12521-12528

Chang Y.-C., Tang K.-C., Pan H.-A., Koshevoy I. O., Karttunen A. J., Chou P.-T., Harvesting Fluorescence from Efficient Reverse Intersystem Crossing for Emissive Transition-Metal Complexes, J. Phys. Chem. C 2013 117(40) 20494-20499

Dau T. M., Shakirova J. R., Domenech A., Janis J., Haukka M., Grachova E. V., Pakkanen T. A., Tunik S. P., Koshevoy I. O., Ferrocenyl-Functionalized Tetranuclear Gold(I) and Gold(I)-Copper(I) Complexes Based on Tridentate Phosphanes, Eur. J. Inorg. Chem. 2013, 28, 4976-4983.

Pirinen S., Koshevoy I. O., Denifl P., Pakkanen T. T., A Single-Crystal Model for MgCl2-Electron Donor Support Materials: [Mg3Cl5(THF)4Bu]2 (Bu = n-Butyl), Organometallics 2013, 32, (15), 4208-4213.

Shakirova J. R., Grachova E. V., Melnikov A. S., Gurzhiy V. V., Tunik S. P., Haukka M., Pakkanen T. A., Koshevoy I. O., Toward Luminescence Vapochromism of Tetranuclear AuI-CuI Clusters, Organometallics 2013, 32, (15), 4061-4069.

Chang Y.-C., Tang K.-C., Pan H.-A., Liu S.-H., Koshevoy I. O., Karttunen A. J., Hung W.-Y., Cheng M.-H., Chou P.-T., Harnessing fluorescence versus phosphorescence branching ratio in (Phenyl)n bridged (n = 0-5) bimetallic Au(I) complexes, J. Phys. Chem. C 2013, 117, (19), 9623-9632.

Makarova A. A., Grachova E. V., Krupenya D. V., Vilkov O., Fedorov A., Usachov D., Generalov A., Koshevoy I. O., Tunik S. P., Ruehl E., Laubschat C., Vyalikh D. V., Self-Assembled Supramolecular Complexes with "Rods-in-Belt" Architecture in the Light of Soft X-rays, J. Phys. Chem. C 2013, 117, (23), 12385-12392.

Koshevoy I. O., Chang Y.-C., Karttunen A. J., Shakirova J. R., Janis J., Haukka M., Pakkanen T., Chou P.-T., Solid-State luminescence of Au-Cu-Alkynyl complexes induced by metallophilicity-driven aggregation, Chem. Eur. J. 2013, 19, (16), 5104-5112.

Krytchankou I. S., Krupenya D. V., Gurzhiy V. V., Belyaev A. A., Karttunen A. J., Koshevoy I. O., Melnikov A. S., Tunik S. P., Synthesis, characterization and photophysical properties of gold(I)-copper(I) alkynyl clusters with 1,4-bis(diphenylphosphino)butane, effect of the diphosphine ligand on luminescence characteristics, J. Organomet. Chem. 2013, 723, 65-71.

Koshevoy I. O., Karttunen A. J., Kritchenkou I. S., Krupenya D. V., Selivanov S. I., Melnikov A. S., Tunik S. P., Haukka M., Pakkanen T. A., Sky-Blue Luminescent AuI-AgI Alkynyl-Phosphine Clusters, Inorg. Chem. 2013, 52, (7), 3663-3673.

Dereza P. Y., Krytchankou I. S., Krupenya D. V., Gurzhiy V. V., Koshevoy I. O., Melnikov A. S., Tunik S. P., Synthesis, structural characterization, and photophysical properties of AuI-CuI heterometallic alkynyl cluster complexes containing N-protected amino acid groups, Z. Anorg. Allg. Chem. 2013, 639, (2), 398-402.


2012

Smirnova E. S., Melekhova A. A., Gurzhiy V. V., Selivanov S. I., Krupenya D. V., Koshevoy I. O., Tunik S. P., Synthesis, structure, and photophysical properties of the Di- and trinuclear phosphine-diimine complexes of copper(I), Z. Anorg. Allg. Chem. 2012, 638, (2), 415-422.

Shakirova J. R., Grachova E. V., Gurzhiy V. V., Koshevoy I. O., Melnikov A. S., Sizova O. V., Tunik S. P., Laguna A., Luminescent heterometallic gold-copper alkynyl complexes stabilized by tridentate phosphine, Dalton Trans. 2012, 41, (10), 2941-2949.

Shakirova J. R., Grachova E. V., Melekhova A. A., Krupenya D. V., Gurzhiy V. V., Karttunen A. J., Koshevoy I. O., Melnikov A. S., Tunik S. P., Luminescent AuI-CuI triphosphane clusters that contain extended linear arylacetylenes, Eur. J. Inorg. Chem. 2012, (25), 4048-4056.

Monakhov K. Y., Grachova E. V., Starova G. L., Zessin T., Linti G., The solid-state, solution and gas-phase interactions of diphosphane monooxide spacers with heavier group 8,9 transition metals and gallium in novel organometallic assemblies: An experimental and computational study, J. Organomet. Chem. 2012, 714, 22-31.

Manshina A. A., Povolotskiy A. V., Povolotskaya A. V., Ivanova T. Y., Koshevoy I. O., Tunik S. P., Suvanto M., Pakkanen T. A., Laser-induced heterometallic phase deposition from solutions of supramolecular complexes, Surf. Coat. Technol. 2012, 206, (16), 3454-3458.

Koshevoy I. O., Chang Y.-C., Karttunen A. J., Selivanov S. I., Janis J., Haukka M., Pakkanen T., Tunik S. P., Chou P.-T., Intensely luminescent homoleptic alkynyl decanuclear gold(I) clusters and their cationic octanuclear phosphine derivatives, Inorg. Chem. 2012, 51, (13), 7392-7403.

Koshevoy I. O., Lin C.-L., Hsieh C.-C., Karttunen A. J., Haukka M., Pakkanen T. A., Chou P.-T., Synthesis, characterization and photophysical properties of PPh2-C2-(C6H4)n-C2-PPh2 based bimetallic Au(i) complexes, Dalton Trans. 2012, 41, (3), 937-945.

Koshevoy I. O., Chang Y.-C., Karttunen A. J., Haukka M., Pakkanen T., Chou P.-T., Modulation of metallophilic bonds: Solvent-induced isomerization and luminescence vapochromism of a polymorphic Au-Cu cluster, J. Am. Chem. Soc. 2012, 134, (15), 6564-6567.

Domenech-Carbo A., Koshevoy I. O., Montoya N., Pakkanen T. A., Domenech-Carbo M. T., Solvent-independent electrode potentials of solids undergoing insertion electrochemical reactions: Part II. Experimental data for alkynyl-diphosphine dinuclear Au(I) Complexes undergoing electron exchange coupled to anion exchange, Journal of Physical Chemistry C 2012, 116, (49), 25984-25992.

Camara J., Crespo O., Gimeno M. C., Koshevoy I. O., Laguna A., Ospino I., Smirnova E. S., Tunik S. P., Emission tuning in dinuclear gold complexes with diphosphanes containing alkyne and/or oligophenylene spacers, Dalton Trans. 2012, 41, (45), 13891-13898.


2011

Koshevoy I. O., Lin C.-L., Karttunen A. J., Janis J., Haukka M., Tunik S. P., Chou P.-T., Pakkanen T. A., Stepwise 1D growth of luminescent Au(I)-Ag(I) phosphine-alkynyl clusters: Synthesis, photophysical, and theoretical studies, Inorg. Chem. 2011, 50, (6), 2395-2403.

Koshevoy I. O., Lin C.-L., Karttunen A. J., Haukka M., Shih C.-W., Chou P.-T., Tunik S. P., Pakkanen T. A., Octanuclear gold(i) alkynyl-diphosphine clusters showing thermochromic luminescence, Chem. Commun. 2011, 47, (19), 5533-5535.

Koshevoy I. O., Smirnova E. S., Haukka M., Laguna A., Chueca J. C., Pakkanen T. A., Tunik S. P., Ospino I., Crespo O., Synthesis, structural characterization, photophysical properties and theoretical analysis of gold(I) thiolate-phosphine complexes, Dalton Trans. 2011, 40, (28), 7412-7422.

Koshevoy I. O., Shakirova J. R., Melnikov A. S., Haukka M., Tunik S. P., Pakkanen T. A., Coinage metal complexes of 2-diphenylphosphino-3-methylindole, Dalton Trans. 2011, 40, (31), 7927-7933.

Koshevoy I. O., Lin C.-L., Karttunen A. J., Janis J., Haukka M., Tunik S. P., Chou P.-T., Pakkanen T. A., Highly luminescent octanuclear AuI-CuI clusters adopting two structural motifs: The effect of aliphatic alkynyl ligands, Chem. Eur. J. 2011, 17, (41), 11456-11466. ON COVER

Grachova E. V., Vologzhanina A. V., Smirnova E. S., Tunik S. P., Synthesis and crystal structure of Na4[Er2(EDTA)2(C2O4)] 8H2O (where EDTA stands for ethylenediamine-N,N-tetraacetate), Russ. J. Inorg. Chem. 2011, 56, (7), 1046-1049.

Domenech A., Koshevoy I. O., Montoya N., Pakkanen T. A., Estimation of free energies of anion transfer from solid-state electrochemistry of alkynyl-based Au(I) dinuclear and Au(I)-Cu(I) cluster complexes containing ferrocenyl groups, Electrochem. Commun. 2011, 13, (1), 96-98.

Domenech A., Koshevoy I. O., Montoya N., Karttunen A. J., Pakkanen T. A., Determination of individual gibbs energies of anion transfer and excess gibbs energies using an electrochemical method based on insertion electrochemistry of solid compounds, J Chem Eng Data 2011, 56, (12), 4577-4586.


2010 - 2006

Ponomarenko V. I., Grachova E. V., Koshevoi I. O., Gindin V. A., Tunik S. P., Pursiainen I., Haukka M., Reaction of chiral pyrrolylphosphine with polynuclear carbonyl complexes of osmium and rhodium, Russ. J. Gen. Chem. 2010, 80, (3), 408-413.

Pennon D., Koshevoy I. O., Estevan F., Sanau M., Ubeda M. A., Perez-Prieto J., Synthesis of a new C3-symmetric tripodal P4-tetradentate ligand and its application to the formation of chiral metal complexes, Organometallics 2010, 29, (3), 703-706.

Koshevoy I. O., Lin Y.-C., Chen Y.-C., Karttunen A. J., Haukka M., Chou P.-T., Tunik S. P., Pakkanen T. A., Rational reductive fusion of two heterometallic clusters: Formation of a highly stable, intensely phosphorescent Au-Ag aggregate and application in two-photon imaging in human mesenchymal stem cells, Chem. Commun. 2010, 46, (9), 1440-1442.

Koshevoy I. O., Karttunen A. J., Lin Y.-C., Lin C.-C., Chou P.-T., Tunik S. P., Haukka M., Pakkanen T. A., Synthesis, photophysical and theoretical studies of luminescent silver(i)-copper(i) alkynyl-diphosphine complexes, Dalton Trans. 2010, 39, (9), 2395-2403.

Koshevoy I. O., Karttunen A. J., Tunik S. P., Janis J., Haukka M., Melnikov A. S., Serdobintsev P. Y., Pakkanen T. A., Reversible protonation of amine-functionalized luminescent Au-Cu clusters: Characterization, photophysical and theoretical studies, Dalton Trans. 2010, 39, (10), 2676-2683.

Koshevoy I. O., Koskinen L., Smirnova E. S., Haukka M., Pakkanen T. A., Melnikov A. S., Tunik S. P., Synthesis, structural characterization and luminescence studies of di- and trinuclear gold(I) alkynyl-phosphine complexes, Z. Anorg. Allg. Chem. 2010, 636, (5), 795-802.

Koshevoy I. O., Ostrova P. V., Karttunen A. J., Melnikov A. S., Khodorkovskiy M. A., Haukka M., Janis J., Tunik S. P., Pakkanen T. A., Assembly of the heterometallic Au(I)-M(I) (M = Cu, Ag) clusters containing the dialkyne-derived diphosphines: Synthesis, luminescence and theoretical studies, Dalton Trans. 2010, 39, (38), 9022-9031.

Koshevoy I. O., Karttunen A. J., Shakirova J. R., Melnikov A. S., Haukka M., Tunik S. P., Pakkanen T. A., Halide-directed assembly of multicomponent systems: Highly ordered AuI-AgI molecular aggregates, Angew. Chem. Int. Ed. 2010, 49, (47), 8864-8866.

Koshevoy I. O., Haukka M., Selivanov S. I., Tunik S. P., Pakkanen T. A., Assembly of the Au-diphosphine helical cage molecules via alkynyl-4-methylydine ligand transformation, Chem. Commun. 2010, 46, (47), 8926-8928.

Heaton B. T., Iggo J. A., Podkorytov I. S., Ponomarenko V. I., Selivanov S. I., Tunik S. P., A rare example of a di-cationic hydrido carbonyl tetra-nuclear cluster, [H2Rh2Pt2(CO)7(PPh3)3]2+, Inorg. Chim. Acta 2010, 363, (3), 549-554.

Domenech A., Koshevoy I. O., Montoya N., Pakkanen T. A., Electrochemical anion sensing using electrodes chemically modified with Au(I)-Cu(I) heterotrimetallic alkynyl cluster complexes containing ferrocenyl groups, Anal. Bioanal. Chem. 2010, 397, (5), 2013-2022.

Bonet A., Gulyas H., Koshevoy I. O., Estevan F., Sanau M., Ubeda M. A., Fernandez E., Tandem beta-boration/arylation of unsaturated carbonyl compounds by using a single palladium complex to catalyse both steps, Chem. Eur. J. 2010, 16, (21), 6382-6390.

Serezhkin V. N., Vologzhanina A. V., Serezhkina L. B., Smirnova E. S., Grachova E. V., Ostrova P. V., Antipin M. Y., Crystallochemical formula as a tool for describing metal-ligand complexes - A pyridine-2,6-dicarb-oxylate example, Acta Crystallogr. Sect. B Struct. Sci. 2009, 65, (1), 45-53.

Ponomarenko V. I., Krupenya D. V., Grachova E. V., Gindin V. A., Selivanov S. I., Koshevoy I. O., Tunik S. P., Haukka M., Pursiainen J., Pirila P., Structure, stereochemistry and dynamics of tetranuclear polyhydride clusters containing chiral heterobidentate phosphanes, Z. Anorg. Allg. Chem. 2009, 635, (15), 2515-2526.

Pakal'nis V. V., Sokolov A. Y., Slisenko A. A., Borovitov M. E., Tunik S. P., Sizova O. V., Synthesis and spectral characteristics of a novel heterometallic binuclear complex on the basis of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine, Russ. J. Gen. Chem. 2009, 79, (5), 980-984.

Lin Y.-C., Chou P.-T., Koshevoy I. O., Pakkanen T. A., Studies of two-photon property of intensely luminescent alkynyl-phosphine Gold(I)-Copper(I) complexes, J Phys Chem A 2009, 113, (33), 9270-9276.

Koshevoy I. O., Lin Y.-C., Karttunen A. J., Chou P.-T., Vainiotalo P., Tunik S. P., Haukka M., Pakkanen T. A., Intensely luminescent alkynyl - Phosphine Gold(l) - Copper(l) complexes: Synthesis, characterization, photophysical, and computational studies, Inorg. Chem. 2009, 48, (5), 2094-2102.

Koshevoy I. O., Karttunen A. J., Tunik S. P., Haukka M., Selivanov S. I., Melnikov A. S., Serdobintsev P. Y., Pakkanen T. A., Synthesis, characterization, photophysical, and theoretical studies of supramolecular gold(i) - silver(i) alkynyl-phosphine complexes, Organometallics 2009, 28, (5), 1369-1376.

Koshevoy I. O., Gutierrez-Puebla E., Lahuerta P., Monge A., Ubeda M. A., Sanau M., Isolation of enantiomerically pure organometallic palladium compounds: Synthesis of the triangles prepared from enantiopure [cis-Pd2(C 6H4PPh2)2(NCCH3) 4]2+, Dalton Trans. 2009, (16), 2993-2998.

Koshevoy I. O., Lin Y.-C., Karttunen A. J., Haukka M., Chou P.-T., Tunik S. P., Pakkanen T. A., An intensely and oxygen independent phosphorescent gold(i)-silver(i) complex: "trapping" an Au8Ag10 oligomer by two gold-alkynyl-diphosphine molecules, Chem. Commun. 2009, (20), 2860-2862.

Koshevoy I. O., Smirnova E. S., Domenech A., Karttunen A. J., Haukka M., Tunik S. P., Pakkanen T. A., Synthesis, electrochemical and theoretical studies of the Au(i)-Cu(i) heterometallic clusters bearing ferrocenyl groups, Dalton Trans. 2009, (39), 8392-8398.

Grachova E. V., Linti G., Protasova I. D., Tunik S. P., Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+: Synthesis, structural and spectroscopic study, Z. Anorg. Allg. Chem. 2009, 635, (13-14), 2294-2296.

Penno D., Lillo V., Koshevoy I. O., Sanau M., Ubeda M. A., Lahuerta P., Fernandez E., Multifaceted palladium catalysts towards the tandem diboration-arylation reactions of alkenes, Chem. Eur. J. 2008, 14, (34), 10648-10655.

Pakal'nis V. V., Borovitov M. E., Balova I. A., Tunik S. P., Ivanova N. V., Sizova O. V., Heteroligand bipyridyl-pyridylbenzimidazole Ru(II) complexes. Synthesis, structural characterization, and investigation of electronic structure, Russ. J. Gen. Chem. 2008, 78, (8), 1594-1605.

Koshevoy I. O., Koskinen L., Haukka M., Tunik S. P., Serdobintsev P. Y., Melnikov A. S., Pakkanen T. A., Self-assembly of supramolecular luminescent AuI-CuI complexes: "Wrapping" an Au6Cu6 cluster in a [Au3(diphosphine)3]3+ "Belt", Angew. Chem. Int. Ed. 2008, 47, (21), 3942-3945.

Koshevoy I. O., Karttunen A. J., Tunik S. P., Haukka M., Selivanov S. I., Melnikov A. S., Serdobintsev P. Y., Khodorkovskiy M. A., Pakkanen T. A., Supramolecular luminescent gold(I)-copper(I) complexes: Self-assembly of the AuxCuy clusters inside the [Au 3(diphosphine)3]3+ triangles, Inorg. Chem. 2008, 47, (20), 9478-9488.

Domenech A., Koshevoy I. O., Penno D., Ubeda M. A., Electrochemical chiral recognition by microparticle coatings of Pd complexes with bridging cyclometalated phosphines, Electrochim Acta 2008, 53, (8), 3416-3426.

Babij C., Farrar D. H., Poe A. J., Tunik S. P., Kinetic study of the reaction of [Rh6(CO)16] with NO2-: Insertion of the nitrogen atom into a Rh6 cluster core, Dalton Trans. 2008, (43), 5922-5929.

Tomashevskaya M. M., Tunik S. P., Podkorytov I. S., Heaton B. T., Iggo J. A., Haukka M., Pakkanen T. A., Pirila P. L., Pursiainen J., A novel heterobidentate chiral phosphine and its coordination chemistry in transition metal clusters, J. Organomet. Chem. 2007, 692, (14), 2911-2923.

Moberg V., Haukka M., Koshevoy I. O., Ortiz R., Nordlander E., Unprecedented enantioselectivity in a cluster-based catalytic system, Organometallics 2007, 26, (17), 4090-4093.

Manshina A. A., Povolotskiy A. V., Ivanova T. Y., Tver'Yanovich Y. S., Tunik S. P., Kim D., Kim M., Kwon S. C., Effect of salt precursor on laser-assisted copper deposition, Appl Phys A 2007, 89, (3), 755-759.

Grachova E. V., Linti G., Stammler H.-G., Neumann B., Tunik S. P., Wadepohl H., Reactions of GaCp* with a hemilabile derivative of Rh6(CO)16 - Synthesis and structural characterization of two novel heterometallic clusters: Rh6(CO)13(3-Ph2PC2H3), Eur. J. Inorg. Chem. 2007, (1), 140-146.

Grachova E. V., Linti G., Reactivity of InCp* towards transition metal carbonyl clusters: Synthesis and structural characterization of the Rh6(CO)16-x(InCp*)x mixed-metal cluster compounds, x = 1-2, Eur. J. Inorg. Chem. 2007, (22), 3561-3564.

Andreev I. A., Grachova E. V., Tunik S. P., Oparina L. A., Sukhov B. G., Malysheva S. F., Kinoshita I., Nishioka T., Structure and dynamic properties of substituted carbonylhydride clusters H2RuOs3(CO)13 and H4Ru 4(CO)12 containing functionalized phosphines, Russ. Chem. Bull. 2007, 56, (7), 1343-1350.

Ponomarenko V. I., Pilyugina T. S., Khripun V. D., Grachova E. V., Tunik S. P., Haukka M., Pakkanen T. A., Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products, J. Organomet. Chem. 2006, 691, (1-2), 111-121.

Koshevoy I. O., Lahuerta P., Sanau M., Ubeda M. A., Domenech A., Dinuclear palladium(II) compounds with bridging cyclometalated phosphines. Synthesis, crystal structure and electrochemical study, Dalton Trans. 2006, (46), 5536-5541.

Koshevoy I. O., Haukka M., Pakkanen T. A., Tunik S. P., Synthesis of nonanuclear heterometallic carbide clusters. Unexpected formation of the [Ru6(CO)16]2-[Pt 2(CO)2(dppm)2]2+ ion pair on the way to [Ru6C(CO)16Pt3(dppm)2], Dalton Trans. 2006, (47), 5641-5647.

Grachova E. V., Krupenya D. V., Pilyugina T. S., Tunik S. P., Pursiainen J., Haukka M., Reactions of carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of H4Ru4(CO)10[k2(P,S)-Ph2P(2-CH3SC 6H4)] and Rh6(CO)14[k2(P,S)-Ph2P(2-CH3SC6H4)] clusters, Russ. J. Gen. Chem. 2006, 76, (5), 682-686.

Cotton F. A., Koshevoy I. O., Lahuerta P., Murillo C. A., Sanau M., Ubeda M. A., Zhao Q., High yield syntheses of stable, singly bonded Pd26+ compounds, J. Am. Chem. Soc. 2006, 128, (42), 13674-13675.


2005 - 2001

Trofimov B. A., Gusarova N. K., Sukhov B. G., Malysheva S. F., Tarasova O. A., Belogorlova N. A., Maximova M. A., Tunik S. P., Atom-economic, solvent-free, high yield synthesis of 2-(pyrrol-1-yl) propyldiorganylphosphines, Synthesis 2005, (6), 965-970.

Koshevoy I. O., Haukka M., Pakkanen T. A., Tunik S. P., Vainiotalo P., Supermolecular assembly of tetra- And hexanuclear carbonyl clusters using a novel polydentate pyridylphosphine ligand, Organometallics 2005, 24, (14), 3516-3526.

Koshevoy I. O., Sizova O. V., Tunik S. P., Lough A., Poe A. J., A novel five-coordinate rhodium(I) complex, Eur. J. Inorg. Chem. 2005, (22), 4516-4520.

Grachova E. V., Jutzi P., Neumann B., Stammler H.-G., Novel rhodium and ruthenium carbonyl cluster complexes with face-and edge-bridging GaCp* ligands. Synthesis and structural characterization of the Rh6(CO)12(GaCp*)4 and Ru6(CO)13(GaCp*)2(GaCp*) clusters, Dalton Trans. 2005, (22), 3614-3616.

Baranovski V. I., Tunik S. P., Korolkov D. V., Quantum chemical study of the addition effect on the geometry of the [Mo6S8(CN)6]6- cluster, Inorg. Chem. Commun. 2005, 8, (3), 242-245.

Babij C., Farrar D. H., Koshevoy I. O., Poe A. J., Tunik S. P., Kinetic studies of some substituted hexarhodium carbonyl clusters, Dalton Trans. 2005, (1), 116-122.

Tunik S. P., Pilyugina T. S., Koshevoy I. O., Selivanov S. I., Haukka M., Pakkanen T. A., Reaction of (S)-BINAP with H4Ru4(CO)12. The first example of face-bridging BINAP coordination and 100% stereoselectivity in formation of a chiral tetranuclear cluster framework, Organometallics 2004, 23, (3), 568-579.

Tunik S. P., Khripun V. D., Haukka M., Pakkanen T. A., Reactions of 2,4-hexadiyne-1,6-diol with [H2Os3(CO)9(PR3)] clusters. Cyclization of the diyne and reversible exchange of the phosphine ligands between different positions of the "Os3C3" framework, Dalton Trans. 2004, (11), 1775-1782.

Tunik S. P., The chemistry of carbonyl clusters of transition metals containing labile and hemilabile ligands. Synthesis, reactivity, and prospects for application, Russ. Chem. Bull. 2004, 53, (12), 2657-2669.

Trofimov B. A., Sukhov B. G., Malysheva S. F., Belogorlova N. A., Arbuzova S. N., Tunik S. P., Gusarova N. K., Synthesis of tertiary bisphosphine oxides from methylacetylene and secondary phosphine oxides, Russ. J. Org. Chem. 2004, 40, (1), 129-130.

Trofimov B. A., Sukhov B. G., Malysheva S. F., Belogorlova N. A., Tantsirev A. P., Parshina L. N., Oparina L. A., Tunik S. P., Gusarova N. K., Addition of secondary phosphines to a vinyl ether of diacetone-d-glucose: A new approach to optically active phosphines and their derivatives, Tetrahedron Lett. 2004, 45, (49), 9143-9145.

Krupenya D. V., Selivanov S. I., Tunik S. P., Haukka M., Pakkanen T. A., The synthesis, structure and dynamic behaviour of disubstituted alkenylphosphine derivatives of [Rh6(CO)16], Dalton Trans. 2004, (16), 2541-2549.

Koshevoy I. O., Tunik S. P., Poe A. J., Lough A., Pursiainen J., Pirila P., A chiral bis(oxazoline) phosphine with a rigid backbone: Ligand synthesis and characterization of products obtained in highly diastereoselective reactions with a rhodium(I) complex and a tetrahedral "RhRu3" cluster, Organometallics 2004, 23, (11), 2641-2650.

Koshevoy I. O., Grachova E. V., Tunik S. P., Haukka M., Pakkanen T. A., Heaton B. T., Iggo J. A., Podkorytov I. S., Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppni)2], Dalton Trans. 2004, (22), 3893-3899.

Heaton B. T., Iggo J. A., Podkorytov I. S., Tunik S. P., Application of HMQC spectroscopy to the observation of the metal resonance in polymetallic compounds: The effect of multiple-metal spin transitions, Magn. Reson. Chem. 2004, 42, (9), 769-775.

Babij C., Chen L., Koshevoy I. O., Poe A. J., QALE analysis of CO dissociative kinetics of Ru(CO)4L (L = P-donor ligands): Accelerating effects of hydrogen in PHnR3-n ligands (n = 1-2), Dalton Trans. 2004, (5), 833-838.

Tunik S. P., Koshevoy I. O., Poe A. J., Farrar D. H., Nordlander E., Haukka' M., Pakkanen T. A., Chiral hexarhodium carbonyl clusters containing heterobidentate phosphine ligands; a structural and reactivity study, Dalton Trans. 2003, (12), 2457-2467.

Tunik S. P., Khripoun V. D., Balova I. A., Borovitov M. E., Domnin I. N., Nordlander E., Haukka M., Pakkanen T. A., Farrar D. H., Reactions of [H2Os3(CO)10] with conjugated diynes (RC2C2R) containing nucleophilic oxygen in І position of a substituent (R = Ph, І = CH2OH, C(O)Ph; R = І = CMe2(OH)), Organometallics 2003, 22, (17), 3455-3465.

Krupenya D. V., Danilov E. O., Rodgers M. A. J., Tunik S. P., Reaction intermediates in the solution photochemistry of a tetrarhodium carbonyl cluster: FTIR structural characterization and transient kinetics, J Phys Chem A 2003, 107, (42), 8867-8871.

Grachova E. V., Haukka M., Heaton B. T., Nordlander E., Pakkanen T. A., Podkorytov I. S., Tunik S. P., The structure and dynamic behaviour of disubstituted derivatives of [Rh 6(CO) 16] containing heterobidentate bridging phosphine ligands, Dalton Trans. 2003, (12), 2468-2473.

Farrar D. H., Grachova E. V., Haukka M., Heaton B. T., Iggo J. A., Pakkanen T. A., Podkorytov I. S., Tunik S. P., The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing bidentate phosphorus ligands, Inorg. Chim. Acta 2003, 354, 11-20.

Tunik S. P., Balova I. A., Borovitov M. E., Nordlander E., Haukka M., Pakkanen T. A., Unusual C-H bond activation - Aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster, J. Chem. Soc. Dalton Trans. 2002, (6), 827-828.

Koshevoy I. O., Tunik S. P., Jaaskelainen S., Haukka M., Pakkanen T. A., Podkorytov I. S., Synthesis and structural characterization of mixed-metal Pt-Rh clusters. Assembly of tetra- and tetra-hexanuclear clusters from smaller metal fragments, J. Chem. Soc. Dalton Trans. 2002, (13), 2768-2774.

Grachova E. V., Jutzi P., Neumann B., Schebaum L. O., Stammler H.-G., Tunik S. P., Unusual selective substitution of triply bridging carbonyl ligands for GaCp* in Rh6(CO)16. Synthesis and structural characterization of the Rh6(CO)4 - x(GaCp*)x(CO)12 clusters, x = 1-4, J. Chem. Soc. Dalton Trans. 2002, (3), 302-304.

Babij C., Browning C. S., Farrar D. H., Koshevoy I. O., Podkorytov I. S., Poe A. J., Tunik S. P., Tripyrrolylphosphine as a unique bridging ligand in the Rh6(CO)14(P(NC4H4)3 cluster: Structure, bonding, fluxionality, thermodynamics, and kinetics studies, J. Am. Chem. Soc. 2002, 124, (30), 8922-8931.

Tunik S. P., Khripun V. D., Balova I. A., Nordlander E., Haukka M., Pakkanen T. A., Raithby P. R., Reactions of diacetylene ligands with trinuclear clusters. 3. Cyclization of diynes with amino moieties on the metal core of [H2Os3(CO)10], Organometallics 2001, 20, (18), 3854-3863.

Sizova O. V., Sizov V. V., Tunik S. P., Quantum-chemical study of organophosphorus ligands coordinated to chromium and nickel carbonyls, Russ. J. Gen. Chem. 2001, 71, (1), 50-57.

Koshevoy I. O., Tunik S. P., Jaaskelainen S., Haukka M., Pakkanen T. A., Linkage of heteronuclear rhodium-platinum clusters, J. Chem. Soc. Dalton Trans. 2001, (20), 2965-2967.

Kiriakidou-Kazemifar N. K., Haukka M., Pakkanen T. A., Tunik S. P., Nordlander E., Formation of rhodium carbonyl thiolate dimers via elimination of dihydrogen; Crystal and molecular structure of [Rh2(CO)4(SC6H4CH3)2], J. Organomet. Chem. 2001, 623, (1-2), 65-73.

Grachova E. V., Heaton B. T., Iggo J. A., Podkorytov I. S., Smawfield D. J., Tunik S. P., Whyman R., Stereochemical nonrigidity of [Rh6 (CO)15L] clusters in solution, J. Chem. Soc. Dalton Trans. 2001, (22), 3303-3311.

Farrar D. H., Grachova E. V., Lough A., Patirana C., Poe A. J., Tunik S. P., Ligand effects on the structures of Rh6(CO)15L clusters, J. Chem. Soc. Dalton Trans. 2001, (13), 2015-2019.


2000 - 1996

Heaton B. T., Iggo J. A., Podkorytov I. S., Smawfield D. J., Tunik S. P., Whyman R., Observation of triple-quantum effects in the HMQC spectra of substituted derivatives of Rh6(CO)16, Dalton Trans. 1999, (12), 1917-1919.

Dolgushin F. M., Grachova E. V., Heaton B. T., Iggo J. A., Koshevoy I. O., Podkorytov I. S., Smawfield D. J., Tunik S. P., Whyman R., Yanovskii A. I., Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(CO)5(CO)4(PPh3)3] and [Rh2Pt2(CO)3-(CO)4(PPh3)3]; crystal structure of [Rh2Pt3(CO)5(CO)4(PPh3)3], Dalton Trans. 1999, (10), 1609-1614.

Tunik S. P., Podkorytov I. S., Heaton B. T., Iggo J. A., Sampanthar J., Multinuclear NMR studies on substituted derivatives of Rh6(CO)16 in solution, J. Organomet. Chem. 1998, 550, (1-2), 221-231.

Tunik S. P., Grachova E. V., Podkorytov I. S., Synthesis and Structure of the Carbonyl Nitrite Cluster [Rh6(CO)13(Ph2PCH2PPh2)(NO2)]PPN, Russ. J. Gen. Chem. 1998, 68, (10), 1674-1675.

Poe A. J., Tunik S. P., Dissociative kinetics of 'lightly bonded ligands' L from the clusters Rh6(CO)15L (L= DMSO, NCMe, cyclooctene, THF and EtOH), Inorg. Chim. Acta 1998, 268, (2), 189-198.

Kuznetsov M. A., Kuchuk I. D., Tunik S. P., Photocatalytic Transformations of Tetramethyl-4,5-diphenyl-4,5-bi-3H-pyrazolyl. Synthesis and Photolysis of the First (1-Cyclopropenyl)pyrazole, Russ. J. Org. Chem. 1998, 34, (2), 245-249.

Tunik S. P., Grachova E. V., Denisov V. R., Starova G. L., Nikol'skii A. B., Dolgushin P. M., Yanovsky A. I., Struchkov Y. T., Reactions of diacetylene ligands with trinuclear clusters II. Reactions of hexa-2,4-diyne-1,6-diol and 1,4-diphenyl-1,3-butadiyne with Ru3(CO)12, J. Organomet. Chem. 1997, 536-537, 339-343.

Tunik S. P., Vlasov A. V., Krivykh V. V., Takats J., Cooke J., Washington J., Acetonitrile-substituted derivatives of Rh6(CO)16: Rh6(CO)16-x(NCMe) x (x = 1, 2), Inorganic Syntheses 1997, 239-244.

Tunik S. P., Shipil' P. N., Vlasov A. V., Denisov V. R., Nikols'kii A. B., Dolgushin F. M., Yanovsky A. I., Struchkov Y. T., Reactions of (6-diphenylacetylene) chromiumtricarbonyl complexes with polynuclear carbonyls. III. Reactions of M4(CO)12 (M = Rh, Co) clusters with Cr(CO)3(PhC2Ph), J. Organomet. Chem. 1996, 515, (1-2), 11-17.


Before 1995

Karpov M. G., Tunik S. P., Denisov V. R., Starova G. L., Nikol'skii A. B., Dolgushin F. M., Yanovsky A. I., Struchkov Y. T., Reactions of diacetylene ligands with trinuclear clusters. I Reactions of 2,4-hexadiyne-1,6-diol and its dicobalthexacarbonyl derivatives with H2Os3(CO)10, J. Organomet. Chem. 1995, 485, (1-2), 219-225.

Tunik S. P., Pomogailo S. I., Dzhardimalieva G. I., Pomogailo A. D., Chuev I. I., Aldoshin S. M., Nikol'skii A. B., Preparation and reactivity of metal-containing monomers - 29. Synthesis and molecular structure of vinylpyridine derivatives of Rh6(CO)16, Russ. Chem. Bull. 1994, 42, (5), 937-942.

Tunik S. P., Vlasov A. V., Nikol'skii A. B., Starova G. L., Ooi S., Nakai H., Sato T., Reactions of (diphenylacetylene)chromiumtricarbonyl complexes with polynuclear carbonyls I. Synthesis of Cr(CO)3(diphenylacetylene) complex and its reaction with Co2(CO)8. Crystal and molecular structure of Cr(CO)3(diphenylacetylene )Co2(CO)6, J. Organomet. Chem. 1994, 464, (1), 71-76.

Tunik S. P., Vlasov A. V., Kogdov K. V., Starova G. L., Nikol'skii A. B., Manole O. S., Struchkov Y. T., Synthesis and structural characterization of the isomers of Rh6(CO)14L2 clusters (L = NCME, Py, P(OPh)3), X-ray crystal structure of trans-Rh6(CO)14{P(OPh3)}2, J. Organomet. Chem. 1994, 479, (1-2), 59-72.

Tunik S. P., Krym V. R., Starova G. L., Nikol'skii A. B., Podkorytov I. S., Ooi S., Yamasaki M., Shiro M., Dark and photochemical reactions of Co3Rh(Co)12 with diphenylacetylene. Crystal and molecular structure of the Co3Rh(CO)2(CO)8(PhC 2Ph) cluster, J. Organomet. Chem. 1994, 481, (1), 83-88.

Tunik S. P., Yarmolenko A. I., Nikol'skii A. B., Spectral characterization of intermediates in photochemical and dark reactions of hexanuclear rhodium clusters, Inorg. Chim. Acta 1993, 205, (1), 71-77.

Tunik S. P., Osipov M. V., Nikolskyi A. B., Synthesis and spectroscopic characterization of the heteronuclear diphosphine linked cluster Os3(CO)11(Ph2PCH2PPh2)Rh6(CO)15, J. Organomet. Chem. 1992, 426, (1), 105-107.

Tunik S. P., Vlasov A. V., Gorshkov N. I., Starova G. L., Nikol'skii A. B., Rybinskaya M. I., Batsanov A. S., Struchkov Y. T., Synthesis and characterization of bis-(diphenylphosphinoethane) -substituted hexarhodium clusters: Rh6(CO)14(L)2, J. Organomet. Chem. 1992, 433, (1-2), 189-201.

Tunik S. P., Vlasov A. V., Nikol'skii A. B., Krivykh V. V., Rybinskaya M. I., Photochemical synthesis of nitrile derivatives of Rh6(CO)16, Russ Chem Bull 1989, 37, (12), 2600.



Last update: 30.08.2019; design: Ludmila Kuchina; content: Elena Grachova; (c)2012-2019.